journal article·2018-05-09

Thiadizoloquinoxaline-Based N-Heteroacenes as Active Elements for High-Density Data-Storage Device

Yang Li, Zilong Wang, Cheng Zhang, Peiyang Gu, Wangqiao Chen, Hua Li, Jianmei Lu, Qichun Zhang

ACS Applied Materials & Interfaces· Volume 10· Issue 18
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Abstract

A novel thiadiazoloquinoxaline (TQ)-based donor–acceptor (D–A)-type N-heteroacene (Py-1-TQ) has been demonstrated for promising applications in organic multilevel resistive memory devices. Compared with its counterparts (Py-0-TQ and Py-2-TQ), which show flash-type binary memory behaviors, Py-1-TQ exhibits excellent nonvolatile write-once-read-many-times-type ternary memory effects with high ON2/ON1/OFF current ratios (105.8:103.4:1), which can be attributed to the different electron-withdrawing abilities between the pyrazine unit and TQ species that can induce stepwise D–A charge-transfer processes. These results suggest that TQ-based N-heteroacenes can be potentially useful in ultrahigh-density data-storage devices through the rational D–A tuning.
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Research context

OpenAlex topics: Advanced Memory and Neural Computing · Semiconductor materials and devices · Ferroelectric and Negative Capacitance Devices

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China

School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore

Funding

Ministry of Education - Singapore · Foundation for the Author of National Excellent Doctoral Dissertation of the People's Republic of China · Government of Jiangsu Province · China Scholarship Council · National Natural Science Foundation of China

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