journal article·2018-05-30

Ultrafast Self-Crystallization of High-External-Quantum-Efficient Fluoride Phosphors for Warm White Light-Emitting Diodes

Wenli Zhou, Mu-Huai Fang, Shixun Lian, Ru-Shi Liu

ACS Applied Materials & Interfaces· Volume 10· Issue 21
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Abstract

In this study, we used HF (as good solvent) to dissolve K2GeF6 and K2MnF6 and added ethanol (as poor solvent) to cause ultrafast self-crystallization of K2GeF6:Mn4+ crystals, which had an unprecedentedly high external quantum efficiency that reached 73%. By using the red phosphor, we achieved a high-quality warm white light-emitting diode with color-rendering index of Ra = 94, R9 = 95, luminous efficacy of 150 lm W–1, and correlated color temperature at 3652 K. Furthermore, the good–poor solvent strategy can be used to fast synthesize other fluorides.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Ga2O3 and related materials

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Affiliations

Department of Chemistry, National Taiwan University, Taipei 106, Taiwan

Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research, Ministry of Education, College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China

Department of Mechanical Engineering and Graduate Institute of Manufacturing Technology, National Taipei University of Technology, Taipei 106, Taiwan

Funding

National Natural Science Foundation of China · Ministry of Science and Technology, Taiwan · Education Bureau of Hunan Province

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