journal article·2017-11-29

Metal–Organic Framework-Stabilized CO2/Water Interfacial Route for Photocatalytic CO2 Conversion

Tian Luo, Jianling Zhang, Wei Li, Zhenhong He, Xiaofu Sun, Jinbiao Shi, Dan Shao, Bingxing Zhang, Xiuniang Tan, Buxing Han

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Abstract

Here, we propose a CO 2 /water interfacial route for photocatalytic CO 2 conversion by utilizing a metal–organic framework (MOF) as both an emulsifier and a catalyst. The CO 2 reduction occurring at the CO 2 /water interface produces formate with remarkably enhanced efficiency as compared with that in conventional solvent. The route is efficient, facile, adjustable, and environmentally benign, which is applicable for the CO 2 transformation photocatalyzed by different kinds of MOFs.
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Research context

OpenAlex topics: Advanced Photocatalysis Techniques · Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Beijing 100190, P. R. China

Department of Chemistry, Capital Normal University, Beijing 100048, P. R. China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Sciences

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