Flexible Photocatalytic Composite Film of ZnO-Microrods/Polypyrrole

Zinc oxide (ZnO)-based photoanodes with sunlight photocatalytic activity are widely used in dye-sensitized solar cells. Presently, most of such electrodes are inflexible due to the rigidness of ZnO and substrate, thus hindering their application in flexible electronics. Here, we report a flexible composite film of ZnO microrod arrays and polypyrrole (PPy) featuring significant flexibility, durability, and photocatalytic capability under visible light. In this composite film, the upper section of the ZnO microrods is coated with an approximately 400 nm thick PPy shell, and the lower section of the ZnO microrods is tightly embedded into an underlying PPy base layer, creating an integrated heterogeneous structure. The upper PPy coating shell serves as a photosensitizer for the ZnO-based photocatalysis, while the lower PPy base layer facilitates electron transport to the substrate and mechanically reinforces the ZnO microrod arrays. Under visible light, this facile structure achieves much higher photocatalytic efficiency in comparison to pure ZnO microrod arrays or PPy film, degrading methylene blue at a rate of 0.22%/min. This photocatalytic composite film may find promising applications in flexible solar cells to power stretchable and wearable electronics.