journal article·2010-04-28

Preparation and Characterization of Self-Cleaning Glass for Vehicle with Niobia Nanosheets

Ken-ichi Katsumata, Sohei Okazaki, Christopher E. J. Cordonier, Tetsuya Shichi, Takayoshi Sasaki, Akira Fujishima

Publisher page

Abstract

Self-cleaning glasses were prepared by coating niobia nanosheets and investigated on the performance. The coated glass heated at >450 degrees C had very low turbidity, high hardness, and excellent adhesion properties. Niobia nanosheets ([Nb(3)O(8)](-)) reacted with sodium ions (Na(+)) diffused from the glass into the films to form a crystalline phase of NaNb(3)O(8) and this phase was converted to NaNbO(3) at >450 degrees C. The films exhibited photoinduced hydrophilicity under UV irradiation but low photocatalytic oxidation activity. Excellent self-cleaning ability of the niobia nanosheet coated glass was confirmed by the Taber abrasion test, which is thought to be a candidate as self-cleaning glasses for vehicles.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · TiO2 Photocatalysis and Solar Cells

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, Kanagawa 226-8503 Japan, Technology Research and Development Department, Central Japan Railway Company, 1545-33 Ohyama, Komaki City, Aichi 485-0801 Japan, International Center for Materials Nanoarchitechtonics and Nanoscale Materials Center, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 Japan, Kanagawa Academy of Science and Technology, KSP Building West 614 3-2-1...

References (29)

Show source-provided references
1. Fujishima A. · Nature · 1972 · 238 · 3710.1038/238037a0 ↗
2. Kawai T. · Nature · 1980 · 286 · 47410.1038/286474a0 ↗
3. Schwitzgebel J. · J. Phys. Chem. · 1995 · 99 · 563310.1021/j100015a055 ↗
4. Sunada K. · J. Photochem. Photobiol.. A: Chem. · 2003 · 156 · 22710.1016/S1010-6030(02)00434-3 ↗
5. Sunada K. · Environ. Sci. Technol. · 1998 · 32 · 72610.1021/es970860o ↗
6. Trapalis C. C. · Thin Solid Films · 2003 · 433 · 18610.1016/S0040-6090(03)00331-6 ↗
7. Mills A. · J. Photochem. Photobiol.. A: Chem. · 1997 · 108 · 110.1016/S1010-6030(97)00118-4 ↗
8. Wang R. · Nature · 1997 · 388 · 43110.1038/41233 ↗
9. Wang R. · Adv. Mater. · 1998 · 10 · 13510.1002/(SICI)1521-4095(199801)10:2<135::AID-ADMA135>3.0.CO;2-M ↗
10. Wang R. · J. Phys. Chem. B · 1999 · 103 · 218810.1021/jp983386x ↗
11. Watanabe T. · Thin Solid Films · 1999 · 351 · 26010.1016/S0040-6090(99)00205-9 ↗
12. Fujishima, A., Hashimoto, K., and Watanabe, T.TiO2Photocatalyst, Fundamentals and Applications;BKC Inc.:Tokyo, 1999; p66.
13. Sakai N. · J. Phys. Chem. B · 2006 · 110 · 619810.1021/jp0556916 ↗
14. Shibata T. · Phys. Chem. Chem. Phys. · 2007 · 9 · 241310.1039/b618448k ↗
15. Paz Y. · J. Mater. Res. · 1995 · 10 · 284210.1557/JMR.1995.2842 ↗
16. Paz Y. · J. Mater. Res. · 1997 · 12 · 275910.1557/JMR.1997.0367 ↗
17. Katsumata K. · J. Am. Chem. Soc. · 2009 · 131 · 385610.1021/ja900394x ↗
18. Kudo A. · J. Catal. · 1988 · 111 · 6710.1016/0021-9517(88)90066-8 ↗
19. Domen K. · Catal. Today · 1990 · 8 · 7710.1016/0920-5861(90)87009-R ↗
20. Sayama K. · J. Phys. Chem. · 1991 · 95 · 134510.1021/j100156a058 ↗
21. Abe R. · Chem. Mater. · 1997 · 9 · 217910.1021/cm970284v ↗
22. Zhang G. · Chem. Eng. J. · 2006 · 123 · 5910.1016/j.cej.2006.06.021 ↗
23. Nedjar R. · J. Solid State Chem. · 1987 · 71 · 18210.1016/0022-4596(87)90157-5 ↗
24. Sakowski-Cowley A. C. · Acta Crystallogr., Sect. B · 1969 · 25 · 85110.1107/S0567740869003141 ↗
25. Kruczek M. · Solid State Commun. · 2006 · 137 · 46910.1016/j.ssc.2006.01.001 ↗
26. Bizeto M. A. · J. Mater. Sci. · 2002 · 37 · 26510.1023/A:1013687825874 ↗
27. Shiguihara A. L. · Colloids Surf., A. · 2007 · 295 · 12310.1016/j.colsurfa.2006.08.040 ↗
28. Kaifu, N;Rica Nenpyo (Chronological Scientific Tables);National Astronomical Observatory;Maruzen Co., Ltd:Tokyo, 2004; p485.
29. Katsumata K. · Mater. Sci. Eng., B · 2010 · doi:10.1016/j.m