DataVXACS Applied Materials & InterfacesPaper
journal article·2018-01-31

Simultaneous Microscopic Structure Characteristics of Shape-Memory Effects of Thermo-Responsive Poly(vinylidene fluoride-co-hexafluoropropylene) Inverse Opals

Maohua Quan, Bowen Yang, Jingxia Wang, Haifeng Yu, Xinyu Cao

ACS Applied Materials & Interfaces· Volume 10· Issue 4
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Source abstract

Abstract

This paper presents a simultaneous microscopic structure characteristic of shape-memory (SM) poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) inverse opals together with a bulk PVDF-HFP by scanning electron microscopy (SEM). The materials show a thermo-sensitive micro-SM property, accompanied with a reversible and modulated optical property. The introduction of the inverse opal structure into the shape-memory polymer material renders a recognition ability of the microstructure change aroused from complex environmental signals by an optical signal, which can be simultaneously detected by SEM. Furthermore, this feature was applied as a reversible write/erase of fingerprint pattern through the press-stimulus and solvent-induced effect, together with the changes of morphology/optical signal. This micro-SM property can be attributed to the shrink/swell effect of the polymer chain from external stimuli combined with the microscopic structure of inverse opals. It will trigger a promising way toward designing reversible micro-deformed actuators.
Source: openalex_inverted_index · Quality: baseline

Research context

Polymers

OpenAlex topics: Photochromic and Fluorescence Chemistry · Polydiacetylene-based materials and applications · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

Department of Material Science and Engineering, College of Engineering, Peking University, Beijing 100871, China

CAS Key Laboratory of Bio-Inspired Materials and Interfacial Sciences, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

School of Future Technologies, University of Chinese Academy of Sciences, Yanqihu Campus, Huaibei Town, Huaibei Zhuang Huairou District, Beijing 101407, China

Key Laboratory of Green Printing, Institute of Chemistry Chinese Academy of Sciences, Beijing 100190, China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China

References (43)

Show source-provided references
1. 10.1021/ja205332w10.1021/ja205332w ↗
2. 10.1021/acs.macromol.5b0064610.1021/acs.macromol.5b00646 ↗
3. 10.1021/cm403812y10.1021/cm403812y ↗
4. 10.1021/ma071517z10.1021/ma071517z ↗
5. 10.1002/1521-3773(20020617)41:12<2034::aid-anie2034>3.0.co;2-m10.1002/1521-3773(20020617)41:12<2034::aid-anie2034>3.0.co;2-m ↗
6. 10.1002/adfm.20150539110.1002/adfm.201505391 ↗
7. 10.1038/srep2446210.1038/srep24462 ↗
8. 10.1016/j.polymer.2011.08.00310.1016/j.polymer.2011.08.003 ↗
9. 10.1038/nature0886310.1038/nature08863 ↗
10. 10.1126/science.114559310.1126/science.1145593 ↗
11. 10.1126/science.126168910.1126/science.1261689 ↗
12. 10.1021/jacs.5b1253110.1021/jacs.5b12531 ↗
13. 10.1021/acs.macromol.5b0065410.1021/acs.macromol.5b00654 ↗
14. 10.1021/acs.macromol.7b0048110.1021/acs.macromol.7b00481 ↗
15. 10.1038/nnano.2017.9110.1038/nnano.2017.91 ↗
16. 10.1002/adfm.20160293510.1002/adfm.201602935 ↗
17. 10.1021/acsami.6b0199110.1021/acsami.6b01991 ↗
18. 10.1002/anie.20090709110.1002/anie.200907091 ↗
19. 10.1002/adma.20150397310.1002/adma.201503973 ↗
20. 10.1002/anie.20130895910.1002/anie.201308959 ↗
21. 10.1021/jacs.5b1061210.1021/jacs.5b10612 ↗
22. 10.1038/ncomms851010.1038/ncomms8510 ↗
23. 10.1002/adma.20150083510.1002/adma.201500835 ↗
24. 10.1038/ncomms841610.1038/ncomms8416 ↗
25. 10.1002/adma.20150022510.1002/adma.201500225 ↗
26. 10.1002/adfm.20140349610.1002/adfm.201403496 ↗
27. 10.1002/anie.20161229110.1002/anie.201612291 ↗
28. 10.1016/j.polymer.2014.09.06210.1016/j.polymer.2014.09.062 ↗
29. 10.1002/adma.20030531810.1002/adma.200305318 ↗
30. 10.1039/c6cs00562d10.1039/c6cs00562d ↗
31. 10.1002/adfm.20160522110.1002/adfm.201605221 ↗
32. 10.1002/macp.20050056310.1002/macp.200500563 ↗
33. 10.1002/marc.20100015610.1002/marc.201000156 ↗
34. 10.1002/adma.20039004410.1002/adma.200390044 ↗
35. 10.1002/adma.20030458810.1002/adma.200304588 ↗
36. 10.1016/s0032-3861(00)00517-610.1016/s0032-3861(00)00517-6 ↗
37. 10.1002/adfm.20100119510.1002/adfm.201001195 ↗
38. 10.1021/ja304751k10.1021/ja304751k ↗
39. 10.1002/adma.20130569810.1002/adma.201305698 ↗
40. 10.1002/marc.20090040910.1002/marc.200900409 ↗
41. 10.1002/adma.20150313210.1002/adma.201503132 ↗
42. 10.1039/c5sm00543d10.1039/c5sm00543d ↗
43. 10.1021/am508970k10.1021/am508970k ↗