Self-Healable Superomniphobic Surfaces for Corrosion Protection
Source abstract
Abstract
Corrosion-protective surfaces are of the utmost relevance to ensure long-term stability and reliability of metals and alloys by limiting their interactions with corrosive species, such as water and ions. However, their practical applications are often limited either by the inability to repel low surface tension liquids such as oils and alcohols or by poor mechanical durability. Here, a superomniphobic surface is reported that can display very high contact angles for both high and low surface tension liquids as well as for concentrated acids and bases. Such extreme repellency allowed for approximately 20% of the corrosion rate compared to the conventional superhydrophobic corrosion protective coatings. Furthermore, the superomniphobic surface can autonomously repair mechanical damage at an elevated temperature (60 °C) within a short period of time (60 s), and the surface can restore its intrinsic corrosion protection performance. Such superomniphobic surfaces thus offer a wide range of potential applications, including pipelines, with sustainable corrosion protection and rust inhibitors for steel in reinforced concrete.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Surface Modification and Superhydrophobicity · Advanced Sensor and Energy Harvesting Materials · Silicone and Siloxane Chemistry
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Mechanical Engineering, University of Kansas, Lawrence, Kansas 66045, United States
Green Materials and Processes Group, Korea Institute of Industrial Technology, Ulsan 44413, Republic of Korea
Department of Biomaterials Science, Pusan National University, Miryang 50463, Republic of Korea
Funding
University of Kansas · Korea Institute of Industrial Technology · Kansas Corn Commission
References (42)
Show source-provided references
1. 10.1002/adma.20100268910.1002/adma.201002689 ↗
2. 10.1038/asiamat.2010.13610.1038/asiamat.2010.136 ↗
3. 10.1002/adma.20130298910.1002/adma.201302989 ↗
4. 10.1002/adma.20150104410.1002/adma.201501044 ↗
5. LaQue, F. L. Marine Corrosion: Causes and Prevention; Wiley: Canada, 1975; p 297.
6. Groysman, A. Corrosion for Everybody; Springer Netherlands, 2009; p 134.10.1007/978-90-481-3477-9 ↗
7. Garverick, L. Corrosion in the Petrochemical Industry; ASM International: Ohio, 1994; p 3.
8. 10.1038/nnano.2014.22010.1038/nnano.2014.220 ↗
9. 10.1002/adma.20170139910.1002/adma.201701399 ↗
10. 10.1002/adfm.20160544610.1002/adfm.201605446 ↗
11. 10.1002/adfm.20170741510.1002/adfm.201707415 ↗
12. 10.1021/acssuschemeng.8b0234510.1021/acssuschemeng.8b02345 ↗
13. 10.1038/s41598-017-04651-310.1038/s41598-017-04651-3 ↗
14. 10.1021/acsami.8b1966310.1021/acsami.8b19663 ↗
15. 10.1021/acsami.6b1211910.1021/acsami.6b12119 ↗
16. 10.1002/adfm.20130210910.1002/adfm.201302109 ↗
17. 10.1002/adma.20029002010.1002/adma.200290020 ↗
18. 10.1002/ange.20100125810.1002/ange.201001258 ↗
19. 10.1002/adma.20130613610.1002/adma.201306136 ↗
20. 10.1021/acssuschemeng.8b0063910.1021/acssuschemeng.8b00639 ↗
21. 10.1021/acs.energyfuels.7b0168210.1021/acs.energyfuels.7b01682 ↗
22. 10.1021/ja310517s10.1021/ja310517s ↗
23. 10.1021/acsami.7b0692410.1021/acsami.7b06924 ↗
24. 10.1038/am.2014.3410.1038/am.2014.34 ↗
25. 10.1038/ncomms202710.1038/ncomms2027 ↗
26. 10.1038/s41563-018-0178-210.1038/s41563-018-0178-2 ↗
27. 10.1002/adma.20160352410.1002/adma.201603524 ↗
28. 10.1021/am302541f10.1021/am302541f ↗
29. 10.1016/j.jcis.2015.06.03010.1016/j.jcis.2015.06.030 ↗
30. 10.1002/adfm.20120203010.1002/adfm.201202030 ↗
31. 10.1039/c3gc41384e10.1039/c3gc41384e ↗
32. Craig, B. D.; Anderson, D. S. Handbook of Corrosion Data; ASM international, 1994; pp 19–30.
33. 10.1021/acsami.6b0633310.1021/acsami.6b06333 ↗
34. 10.1016/0095-8522(62)90011-910.1016/0095-8522(62)90011-9 ↗
35. 10.1038/nmat443510.1038/nmat4435 ↗
36. 10.1021/acsomega.8b0263110.1021/acsomega.8b02631 ↗
37. 10.1016/j.electacta.2005.02.14510.1016/j.electacta.2005.02.145 ↗
38. Crank, J. The Mathematics of Diffusion; Oxford University Press: New York, 1979; pp 40–70.
39. 10.1126/science.124484510.1126/science.1244845 ↗
40. 10.1126/science.121264810.1126/science.1212648 ↗
41. Baboian, R. Corrosion Tests and Standards: Application and Interpretation; ASTM: Baltimore, 1995; p 60.
42. 10.1039/tf949450063610.1039/tf9494500636 ↗