journal article·2019-02-06

Resist-Dyed Textile Alkaline Zn Microbatteries with Significantly Suppressed Zn Dendrite Growth

Mengmeng Liu, Xiong Pu, Zifeng Cong, Zhixiao Liu, Ting Liu, Yanghui Chen, Jianqiang Fu, Weiguo Hu, Zhong Lin Wang

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Abstract

The progress of electronic textiles relies on the development of sustainable power sources without much sacrifice of convenience and comfort of fabrics. Herein, we present a rechargeable textile alkaline Zn microbattery (micro-AZB) fabricated by a process analogous to traditional resist-dyeing techniques. Conductive patterned electrodes are realized first by resist-aided electroless/electrodeposition of Ni/Cu films. The resulting coplanar micro-AZB in a single textile, with an electroplated Zn anode and a Ni0.7Co0.3OOH cathode, achieves high energy density (256.2 Wh kg–1), high power density (10.3 kW kg–1), and stable cycling performances (82.7% for 1500 cycles). The solid-state micro-AZB also shows excellent mechanical reliability (bending, twisting, tailoring, etc.). The improved reversibility and cyclability of textile Zn electrodes over conventional Zn foils are found to be due to the significantly inhibited Zn dendrite growth and suppressed undesirable side reactions. This work provides a new approach for energy-storage textile with high rechargeability, high safety, and aesthetic design versatility.
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Research context

OpenAlex topics: Advanced battery technologies research · Conducting polymers and applications · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Center for Excellence in Nanoscience, Beijing Key Laboratory of Micro-Nano Energy and Sensor, Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, China

School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China

Center on Nanoenergy Research, School of Physical Science and Technology, Guangxi University, Nanning 530004, China

College of Materials Science and Engineering, Hunan University, Changsha 410082, China

School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, United States

Funding

Ministry of Science and Technology of the People's Republic of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences · National Natural Science Foundation of China · Chinese Academy of Sciences

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