Fabrication of a Novel Bifunctional Nanocomposite with Improved Selectivity for Simultaneous Nitrate and Phosphate Removal from Water

Phosphorus and nitrogen compounds are both the main sources of eutrophication and coexist in some municipal effluents or eutrophic waters; elimination of phosphorus and nitrogen from wastewater is becoming an imperative but also a hard task. Herein, an innovative bifunctional nanocomposite HFO@TPR was developed for synchronous nitrate/phosphate elimination from water. A macroporous polystyrene microspheres modified with triethylamine functional groups was synthesized as the host of HFO@TPR for selective nitrate removal, and Fe(III) hydroxide (HFO) nanoparticles were implanted inside as the active species for specific phosphate removal. Compared to other commercial adsorbents, HFO@TPR exhibited outstanding selectivity and preference toward nitrates and phosphates, and the coexisting anions exert an insignificant effect on adsorption performance. Such exceptional bifuntionality of HFO@TPR was achieved through two pathways, that is, nitrate was preferentially adsorbed by the fixed triethylamine groups through the electrostatic attraction, and phosphate was preferentially captured by the encapsulated HFO nanoparticles through the inner-sphere complexation. The exhausted HFO@TPR could be effectively regenerated by using a NaOH-NaCl mixed reagent for cyclic use with a relative constant efficiency. In addition, column adsorption experiments demonstrated that HFO@TPR could eliminate nitrate from 18 to <10 mg N/L with the treatment capacity of ∼600 bed volume (BV), and meanwhile remove phosphate from 2.5 to <0.2 mg P/L with the treatment capacity of ∼750 BV. We believe what we found in this study could advance the method on how to develop bifunctional adsorbents for synchronous removal of coexisting contaminants from water.