A Novel Graphdiyne-Based Catalyst for Effective Hydrogenation Reaction
Source abstract
Abstract
The platinum nanoparticles (Pt NPs) hybrided with nanostructured carbon materials with high stability are important for catalyzing hydrogenation reaction. Here we reported the fabrication of ultrastable Pt NPs anchored on graphdiyne, in which the strong interactions induced by the porous graphdiyne can prevent the thermal migration of Pt nanoparticles on the graphdiyne surface, exploiting the strong charge transfer interactions from Pt NPs to GDY substrate to tune the electron density of Pt NPs. Pt NPs catalyst with size of 2-3 nm showed high performance on hydrogenation of aldehydes and ketones to the corresponding alcohols compared with commercial Pt-C. Our results indicated that graphdiyne is a promising substrate for constructing metal nanoparticle-based heterogeneous catalysts, especially for those requiring strong interactions between metal nanoparticles and reactants.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Nanomaterials for catalytic reactions · Asymmetric Hydrogenation and Catalysis · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University, 88 Wenhuadonglu Road, Jinan 250014, P. R. China
Beijing National Laboratory for Molecular Sciences (BNLMS), CAS Key Laboratory of Organic Solids, Institute of Chemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Chinese Academy of Sciences, Beijing 100190, P. R. China
School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, PR China
Funding
Ministry of Science and Technology of the People's Republic of China · Deutsche Forschungsgemeinschaft · National Natural Science Foundation of China · Chinese Academy of Sciences
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