journal article·2010-10-27

Compressed Metal Powders that Remain Superhydrophobic after Abrasion

Iain A. Larmour, Graham C. Saunders, Steven E. J. Bell

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Abstract

Superhydrophobic “lotus effect” materials are typically not sufficiently robust for most real world applications because their small surface features are both easily damaged and vulnerable to fouling. Here, a method for preparing a new type of superhydrophobic (θ > 162°) composite material by compression of superhydrophobic metal particles is reported. This material, which has no natural analogue, has low-surface-energy microstructures extending throughout its whole volume. Removing its outer layer by abrasion or cutting deep into it does not result in loss of superhydrophobicity because it merely exposes a fresh portion of the underlying superhydrophobic material. The high contact angle is therefore retained even after accidental damage, and vigorous abrasion can be used to restore hydrophobicity after fouling.
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Research context

OpenAlex topics: Surface Modification and Superhydrophobicity · Fluid Dynamics and Heat Transfer · Adhesion, Friction, and Surface Interactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Innovative Molecular Materials Group, School of Chemistry and Chemical Engineering, Queen’s University Belfast, Belfast BT9 5AG, United Kingdom

References (31)

Show source-provided references
1. Zhang X. · J. Mater. Chem. · 2008 · 18 · 62110.1039/B711226B ↗
2. Feng X. J. · Adv. Mater. · 2006 · 18 · 306310.1002/adma.200501961 ↗
3. Roach P. · Soft Matter · 2008 · 4 · 22410.1039/B712575P ↗
4. Zhai L. · Nano Lett. · 2006 · 6 · 121310.1021/nl060644q ↗
5. Mock U. · J. Phys.: Condens. Matter · 2005 · 17 · S639
6. Gao L. C. · Langmuir · 2006 · 22 · 599810.1021/la061237x ↗
7. Lau K. K. S. · Nano Lett. · 2003 · 3 · 170110.1021/nl034704t ↗
8. Han J. T. · Langmuir · 2005 · 21 · 666210.1021/la051042+ ↗
9. Shirtcliffe N. J. · Adv. Mater. · 2004 · 16 · 192910.1002/adma.200400315 ↗
10. Nishino T. · Langmuir · 1999 · 15 · 432110.1021/la981727s ↗
11. Quéré D. · Rep. Prog. Phys. · 2005 · 68 · 249510.1088/0034-4885/68/11/R01 ↗
12. Barbieri L. · Langmuir · 2007 · 23 · 172310.1021/la0617964 ↗
13. Qian B. · Langmuir · 2005 · 21 · 900710.1021/la051308c ↗
14. Li M. · J. Phys. Chem. B · 2003 · 107 · 995410.1021/jp035562u ↗
15. Puukilainen E. · Langmuir · 2007 · 23 · 726310.1021/la063588h ↗
16. Onda T. · Langmuir · 1996 · 12 · 212510.1021/la950418o ↗
17. Yamauchi G. · Colloid Surf., A · 1996 · 116 · 12510.1016/0927-7757(96)03653-9 ↗
18. Nakajima A. · Thin Solid Films · 2000 · 376 · 14010.1016/S0040-6090(00)01417-6 ↗
19. Li Z.-M. · Chem. Soc. Rev. · 2007 · 36 · 135010.1039/b602486f ↗
20. Solga A. · Bioinspiration Biomimetics · 2007 · 2 · S12610.1088/1748-3182/2/4/S02 ↗
21. Höhne S. · Macromol. Chem. Phys. · 2009 · 210 · 126310.1002/macp.200900096 ↗
22. Hou W. · J. Colloid Interface Sci. · 2008 · 327 · 12010.1016/j.jcis.2008.07.056 ↗
23. Shirtcliffe N. J. · Langmuir · 2003 · 19 · 562610.1021/la034204f ↗
24. Larmour I. A. · Angew. Chem., Int. Ed. · 2008 · 47 · 504310.1002/anie.200705833 ↗
25. Larmour I. A. · Angew. Chem., Int. Ed. · 2007 · 46 · 171010.1002/anie.200604596 ↗
26. Lazghab M. · Powder Technol. · 2005 · 157 · 7910.1016/j.powtec.2005.05.014 ↗
27. Forward K. M. · Langmuir · 2007 · 23 · 525510.1021/la700471y ↗
28. Although the discs appear solid, they are porous, as indicated by their lower density compared to bulk copper and the fact that discs pressed from untreated copper powder are capable of completely adsorbing water drops placed on their surface within a few seconds.
29. Moreover, the discs displayed a highly reflective “silver mirror” effect when immersed in water and viewed at an oblique angle, because of the substantial air contribution for these Cassie−Baxter surfaces(25, 30).
30. Marmur A. · Langmuir · 2006 · 22 · 140010.1021/la052802j ↗
31. Elices M. · Eng. Fract. Mech. · 2008 · 75 · 383910.1016/j.engfracmech.2008.02.011 ↗