journal article·2018-10-03Open access

One-Pot Synthesis of High-Flux b-Oriented MFI Zeolite Membranes for Xe Recovery

Xuerui Wang, Pelin Karakiliç, Xinlei Liu, Meixia Shan, Arian Nijmeijer, Louis Winnubst, Jorge Gascon, Freek Kapteijn

ACS Applied Materials & Interfaces· Volume 10· Issue 39

Abstract

We demonstrate that b-oriented MFI (Mobil Five) zeolite membranes can be manufactured by in situ crystallization using an intermediate amorphous SiO2 layer. The improved in-plane growth by using a zeolite growth modifier leads to fusion of independent crystals and eliminates boundary gaps, giving good selectivity in the separation of CO2/Xe mixtures. The fast diffusion of CO2 dominates the overall membrane selectivity toward the CO2/Xe mixture. Because of the straight and short [010] channels, the obtained CO2 permeation fluxes are several orders of magnitude higher than those of carbon molecular sieving membranes and polymeric membranes, opening opportunities for Xe recovery from waste anesthetic gas.
Source: europepmc · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Zeolite Catalysis and Synthesis · Membrane Separation and Gas Transport · Chemical Synthesis and Characterization

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Chemical Engineering Department, Delft University of Technology, Van der Maasweg 9, 2629 HZ Delft, The Netherlands

Inorganic Membranes, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands

KAUST Catalysis Center, Advanced Catalytic Materials, King Abdullah University of Science and Technology, Thuwal 23955, Saudi Arabia

Funding

Stichting voor de Technische Wetenschappen

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