journal article·2016-10-26

Structure, Electronic Properties, and Electrochemical Behavior of a Boron-Doped Diamond/Quartz Optically Transparent Electrode

Naihara Wächter, Catherine Munson, Romana Jarošová, Isil Berkun, Timothy Hogan, Romeu C. Rocha-Filho, Greg M. Swain

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Abstract

The morphology, microstructure, chemistry, electronic properties, and electrochemical behavior of a boron-doped nanocrystalline diamond (BDD) thin film grown on quartz were evaluated. Diamond optically transparent electrodes (OTEs) are useful for transmission spectroelectrochemical measurements, offering excellent stability during anodic and cathodic polarization and exposure to a variety of chemical environments. We report on the characterization of a BDD OTE by atomic force microscopy, optical spectroscopy, Raman spectroscopic mapping, alternating-current Hall effect measurements, X-ray photoelectron spectroscopy, and electrochemical methods. The results reported herein provide the first comprehensive study of the relationship between the physical and chemical structure and electronic properties of a diamond OTE and the electrode's electrochemical activity.
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Research context

OpenAlex topics: Diamond and Carbon-based Materials Research · Force Microscopy Techniques and Applications · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Química, Universidade Federal de São Carlos, C. P. 676, 13560-970 São Carlos, SP, Brazil

Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, United States

Department of Computer and Electrical Engineering, Michigan State University, East Lansing, Michigan 48824, United States

Funding

Army Research Office · Czech Science Foundation · Conselho Nacional de Desenvolvimento Científico e Tecnológico · Univerzita Karlova · Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

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