journal article·2018-02-14

Iron-Based Metal–Organic Framework with Hydrophobic Quadrilateral Channels for Highly Selective Separation of Hexane Isomers

Daofei Lv, Hao Wang, Yongwei Chen, Feng Xu, Renfeng Shi, Zewei Liu, Xinlong Wang, Simon J. Teat, Qibin Xia, Zhong Li, Jing Li

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Abstract

A novel iron-based microporous metal–organic framework built of trinuclear iron clusters [Fe 3 (μ 3 -O)(COO) 6 ] and 2,2-bis(4-carboxyphenyl)-hexafluoropropane (6FDCA) has been prepared by solvothermal synthesis. It exhibits excellent chemical stability and strong hydrophobic character. More importantly, this material is capable of separating hexane isomers with good separation performance on the basis of a kinetically controlled process, making it a promising candidate for improving the research octane number of gasoline.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Zeolite Catalysis and Synthesis · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, United States

College of Chemistry, Northeast Normal University, Changchun 130024, P. R. China

Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720, United States

Funding

China Scholarship Council · National Natural Science Foundation of China · Guangdong Province

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