journal article·2020-01-29Open access

Monodisperse CoSn and NiSn Nanoparticles Supported on Commercial Carbon as Anode for Lithium- and Potassium-Ion Batteries

Junshan Li, Xijun Xu, Xiaoting Yu, Xu Han, Ting Zhang, Yong Zuo, Chaoqi Zhang, Dawei Yang, Xiang Wang, Zhishan Luo, Jordi Arbiol, Jordi Llorca, Jun Liu, Andreu Cabot

Abstract

Monodisperse CoSn and NiSn nanoparticles were prepared in solution and supported on commercial carbon black. The obtained nanocomposites were applied as anodes for Li- and K-ion batteries. CoSn@C delivered stable average capacities of 850, 650, and 500 mAh g–1 at 0.2, 1.0, and 2.0 A g–1, respectively, well above those of commercial graphite anodes. The capacity of NiSn@C retained up to 575 mAh g–1 at a current of 1.0 A g–1 over 200 continuous cycles. Up to 74.5 and 69.7% pseudocapacitance contributions for Li-ion batteries were measured for CoSn@C and NiSn@C, respectively, at 1.0 mV s–1. CoSn@C was further tested in full-cell lithium-ion batteries with a LiFePO4 cathode to yield a stable capacity of 350 mAh g–1 at a rate of 0.2 A g–1. As electrode in K-ion batteries, CoSn@C composites presented a stable capacity of around 200 mAh g–1 at 0.2 A g–1 over 400 continuous cycles, and NiSn@C delivered a lower capacity of around 100 mAh g–1 over 300 cycles.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Technologies Research · Supercapacitor Materials and Fabrication

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Catalonia Institute for Energy Research - IREC, Sant Adrià de Besòs, 08930 Barcelona, Spain

Departament d’Electrònica, Universitat de Barcelona, 08028 Barcelona, Spain

Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, P. R. China

SUNWODA-SCUT Joint Laboratory for Advanced Energy Storage Technology, South China University of Technology, Guangzhou 510641, P. R. China

Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST, Campus UAB, Bellaterra, 08193 Barcelona, Spain

Department of Chemistry, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong 518055, P. R. China

ICREA, Pg. Lluís Companys 23, 08010 Barcelona, Spain

Institute of Energy Technologies, Department of Chemical Engineering and Barcelona Research Center in Multiscale Science and Engineering. Universitat Politècnica de Catalunya, EEBE, 08019 Barcelona, Spain

Funding

Ministry of Education of the People's Republic of China · European Regional Development Fund · Ministerio de Econom?a y Competitividad · Generalitat de Catalunya · China Scholarship Council · Universitat Aut?noma de Barcelona · National Natural Science Foundation of China · Instituci? Catalana de Recerca i Estudis Avan?ats · Guangdong Province · Central People's Government of the People's Republic of China

References (56)

Show source-provided references
1. 10.1039/b820555h10.1039/b820555h ↗
2. 10.1016/j.mattod.2014.10.04010.1016/j.mattod.2014.10.040 ↗
3. 10.1021/cr500207g10.1021/cr500207g ↗
4. 10.1039/c0jm04225k10.1039/c0jm04225k ↗
5. 10.1016/j.jmat.2015.06.00210.1016/j.jmat.2015.06.002 ↗
6. 10.1002/smtd.20160003710.1002/smtd.201600037 ↗
7. 10.1021/nn501945f10.1021/nn501945f ↗
8. 10.1002/adfm.20160602310.1002/adfm.201606023 ↗
9. 10.1002/adfm.20150051410.1002/adfm.201500514 ↗
10. 10.1021/acs.nanolett.7b0008310.1021/acs.nanolett.7b00083 ↗
11. 10.1007/s11581-017-2177-810.1007/s11581-017-2177-8 ↗
12. 10.1166/mex.2012.107510.1166/mex.2012.1075 ↗
13. 10.1002/anie.20140953010.1002/anie.201409530 ↗
14. 10.1039/C5NR03093E10.1039/C5NR03093E ↗
15. Kamali A. R. · Rev. Adv. Mater. Sci. · 2011 · 27 · 14
16. 10.1021/acsami.7b0164010.1021/acsami.7b01640 ↗
17. 10.1039/C6NJ02458K10.1039/C6NJ02458K ↗
18. 10.1039/C4TA06862A10.1039/C4TA06862A ↗
19. 10.1021/acsnano.8b0058610.1021/acsnano.8b00586 ↗
20. 10.1016/j.nanoen.2015.05.03510.1016/j.nanoen.2015.05.035 ↗
21. Milanova V. L. · Rev. Adv. Mater. Sci · 2015 · 41 · 52
22. 10.1016/j.electacta.2018.05.02210.1016/j.electacta.2018.05.022 ↗
23. 10.1039/C4RA07520J10.1039/C4RA07520J ↗
24. 10.1002/advs.20170029810.1002/advs.201700298 ↗
25. 10.1039/C7TA00099E10.1039/C7TA00099E ↗
26. 10.1039/C8TA10953B10.1039/C8TA10953B ↗
27. 10.1038/natrevmats.2018.1310.1038/natrevmats.2018.13 ↗
28. 10.1039/C7TA08171E10.1039/C7TA08171E ↗
29. 10.1016/j.electacta.2019.02.09810.1016/j.electacta.2019.02.098 ↗
30. 10.1002/cssc.20180266210.1002/cssc.201802662 ↗
31. 10.1039/C8TA01492B10.1039/C8TA01492B ↗
32. 10.1039/C4NR05604C10.1039/C4NR05604C ↗
33. 10.1039/C5EE02074C10.1039/C5EE02074C ↗
34. 10.3891/acta.chem.scand.40a-002310.3891/acta.chem.scand.40a-0023 ↗
35. 10.1016/j.apcatb.2018.04.01710.1016/j.apcatb.2018.04.017 ↗
36. 10.1021/cm504514410.1021/cm5045144 ↗
37. 10.1039/C8TA08242A10.1039/C8TA08242A ↗
38. 10.1039/C9TA07066D10.1039/C9TA07066D ↗
39. 10.1021/acs.langmuir.5b0462210.1021/acs.langmuir.5b04622 ↗
40. 10.1039/C6TA10535A10.1039/C6TA10535A ↗
41. 10.1021/nl502860610.1021/nl5028606 ↗
42. 10.1021/am508547g10.1021/am508547g ↗
43. 10.1039/C7NR08261D10.1039/C7NR08261D ↗
44. 10.1002/chem.20170222510.1002/chem.201702225 ↗
45. 10.1039/C7NR04786J10.1039/C7NR04786J ↗
46. 10.1039/C6TA03083A10.1039/C6TA03083A ↗
47. 10.1149/1.139155610.1149/1.1391556 ↗
48. 10.1038/nmat261210.1038/nmat2612 ↗
49. 10.1002/adfm.20170757310.1002/adfm.201707573 ↗
50. 10.1149/2.0141505jes10.1149/2.0141505jes ↗
51. 10.1002/adfm.20190384210.1002/adfm.201903842 ↗
52. 10.1038/ncomms792910.1038/ncomms7929 ↗
53. 10.1002/anie.20160746910.1002/anie.201607469 ↗
54. 10.1002/eem2.1202810.1002/eem2.12028 ↗
55. 10.1039/c3ee44164d10.1039/c3ee44164d ↗
56. 10.1002/adfm.20170385710.1002/adfm.201703857 ↗