journal article·2017-12-27

Quasi 2D Mesoporous Carbon Microbelts Derived from Fullerene Crystals as an Electrode Material for Electrochemical Supercapacitors

Qin Tang, Partha Bairi, Rekha Goswami Shrestha, Jonathan P. Hill, Katsuhiko Ariga, Haibo Zeng, Qingmin Ji, Lok Kumar Shrestha

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Abstract

Fullerene C 60 microbelts were fabricated using the liquid–liquid interfacial precipitation method and converted into quasi 2D mesoporous carbon microbelts by heat treatment at elevated temperatures of 900 and 2000 °C. The carbon microbelts obtained by heat treatment of fullerene C 60 microbelts at 900 °C showed excellent electrochemical supercapacitive performance, exhibiting high specific capacitances ca. 360 F g –1 (at 5 mV s –1 ) and 290 F g –1 (at 1 A g –1 ) because of the enhanced surface area and the robust mesoporous framework structure. Additionally, the heat-treated carbon microbelt showed good rate performance, retaining 49% of capacitance at a high scan rate of 10 A g –1 . The carbon belts exhibit super cyclic stability. Capacity loss was not observed even after 10 000 charge/discharge cycles. These results demonstrate that the quasi 2D mesoporous carbon microbelts derived from a π-electron-rich carbon source, fullerene C 60 crystals, could be used as a new candidate material for electrochemical supercapacitor applications.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced battery technologies research · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, 200 Xiaolingwei, Nanjing 210094, China

Supermolecules Group, International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan

Department of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561, Japan

MIIT Key Laboratory of Advanced Display Materials and Devices, Nanjing University of Science and Technology, Nanjing 210094, China

Funding

Ministry of Education of the People's Republic of China · Core Research for Evolutional Science and Technology · Natural Science Foundation of Jiangsu Province · Japan Society for the Promotion of Science · National Natural Science Foundation of China

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