Flexible Zirconium MOF as the Crystalline Sponge for Coordinative Alignment of Dicarboxylates
Source abstract
Abstract
Because of their permanent porosity and unparalleled structural diversities, flexible metal-organic frameworks (MOFs) are promising and highly desirable in host-guest chemistry. In this work, we employed a flexible Zr-MOF system, namely PCN-700 species, as the crystalline sponge for guest inclusion. A family of linear dicarboxylate ligands was adsorbed in the void space of PCN-700, which were subsequently confirmed by crystallographic observation. The stretching degree of the PCN-700 series was varied by means of dicarboxylate encapsulation through coordinative alignment.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Dendrimers and Hyperbranched Polymers
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States
Chemistry Department, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
Funding
ConocoPhillips · Basic Energy Sciences · King Saud University · Dow Chemical Company · Office of Fossil Energy · U.S. Department of Energy
References (43)
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