journal article·2019-11

An experimental investigation: The impact of cobalt doping on optical properties of YbFeO3-ẟ thin film

O. Polat, M. Caglar, F.M. Coskun, M. Coskun, Y. Caglar, A. Turut

Publisher page

Abstract

Abstract It has been shown that the band gap engineering plays vital role in the designing of new semiconductors. Therefore, many research groups have focused on various techniques to tune the band gap such as chemical doping and strain energy. In the present work, polycrystalline YbFeO3- ẟ (YbFO) and YbFe1-xCoxO3- ẟ (YbFCO) (x = 0.01 and 0.10) thin films were grown on indium tin oxide (ITO) substrates at 500 0C by magnetron sputtering technique. The crystalline orientation of the thin films has been studied by XRD. SEM and AFM have been utilized in the surface topographical investigations and XPS analysis was carried out in order to reveal the oxidation states of elements in studied materials. It has been shown that the optical band gap YbFO can be tuned from 2.1 eV to 1.72 eV via Co doping into Fe sites. Furthermore, diffuse reflectance spectroscopy (DRS) has been employed to study reflectance %, refractive index (n), extinction coefficient (k), real and imaginary parts of dielectric constant and conductivity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Multiferroics and related materials · Ferroelectric and Piezoelectric Materials · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (49)

Show source-provided references
1. Band-gap engineering: from physics and materials to new semiconductor devices10.1126/science.235.4785.172 ↗
2. Klingshirn · 2007
3. Engineering the band gap of LaCrO3 doping with transition metals (Co, Pd and Ir)10.1007/s10853-017-1773-3 ↗
4. Os doped YMnO3 multiferroic: a study investigating the electrical properties through tuning the doping level10.1016/j.jallcom.2018.04.200 ↗
5. Electrical characterization of Ir doped rare-earth orthoferrite YbFeO310.1016/j.jallcom.2019.02.141 ↗
6. Chemical structures and performance of perovskite oxides10.1021/cr980129f ↗
7. Co doped YbFeO3: exploring the electrical properties via tuning the doping level
8. Perovskite oxides for visible-light-absorbing ferroelectric and photovoltaic materials10.1038/nature12622 ↗
9. Single photon emitters in exfoliated WSe2 structures10.1038/nnano.2015.67 ↗
10. Colloidal quantum-dot photodetectors exploiting multiexciton generation10.1126/science.1173812 ↗
11. A graphene-based broadband optical modulator10.1038/nature10067 ↗
12. Synthesis, structural and magnetic properties of La1-xCdxFeO3 (0.0≤x≤0.3) orthoferrites10.1016/j.materresbull.2009.02.010 ↗
13. Weak ferromagnetism and superparamagnetic clusters coexistence in YFe1-xCoxO3 (0≤x≤1) perovskites10.1016/j.materresbull.2017.06.045 ↗
14. Electrical and magnetic properties of spherical SmFeO3 synthesized by aspartic acid assisted combustion method10.1016/j.materresbull.2015.07.013 ↗
15. Ferroelectricity and weak ferromagnetism of hexagonal ErFeO3 thin films10.1103/PhysRevB.92.054101 ↗
16. Temperature induced spin switching in SmFeO3 single crystal10.1038/srep05960 ↗
17. Spin reorientation, magnetization reversal, and negative thermal expansion observed in RFe0.5Cr0.5O3 perovskites (R = Lu,Yb,Tm)10.1103/PhysRevB.94.134402 ↗
18. Relationship between structural parameters and the n′eel temperature in Sr1-xCaxMnO3 (0<˜ x<˜ 1) and Sr1-yBayMnO3 (y <˜ 0.2)10.1103/PhysRevB.64.134412 ↗
19. Effect of ionic size on the orbital ordering transition in RMnO3+δ10.1088/1367-2630/6/1/153 ↗
20. Structure and band gap tuning of transparent (Ba1−xSrx)SnO3 thin films epitaxially grown on MgO substrates10.1209/0295-5075/98/47010 ↗
21. Structural effects on the magnetic and transport properties of perovskite A1-xA′xMnO3 (x = 0.25, 0.30)10.1103/PhysRevB.56.8265 ↗
22. Systematic study of insulator-metal transitions in perovskites RNiO3 (R = Pr, Nd, Sm, Eu) due to closing of charge-transfer gap10.1103/PhysRevB.45.8209 ↗
23. Structural, optical and electronic properties of RFeO310.1016/j.ceramint.2018.02.023 ↗
24. Ferroelectricity and ferrimagnetism of hexagonal YbFeO3 thin films10.1143/JPSJ.81.024719 ↗
25. Electronic structure and direct observation of ferrimagnetism in multiferroic hexagonal YbFeO310.1103/PhysRevB.95.224428 ↗
26. XRD and HREM studies of epitaxially stabilized hexagonal orthoferrites RFeO3 (R = Eu−Lu)10.1021/cm0353660 ↗
27. Effect of oxygen partial pressure on the formation of metastable phases from an undercooled YbFeO3 melt using an aerodynamic levitator10.1111/j.1551-2916.2009.02974.x ↗
28. Improved oxide ion conductivity in La0.8Sr0.2Ga0.8Mg0.2O3 by doping Co10.1021/cm981145w ↗
29. Sol-gel synthesis, solid sintering, and thermal stability of single phase YCoO310.1002/pssa.201127710 ↗
30. Porous YFe0.5Co0.5O3 thin sheets as cathode for intermediate-temperature solid oxide fuel cells10.1016/j.ijhydene.2017.05.109 ↗
31. Enhanced switchable ferroelectric photovoltaic effects in hexagonal ferrite thin films via strain engineering10.1021/acsami.7b16700 ↗
32. Effect of gallium doping on the structural, optical and electrical properties of zinc oxide thin films prepared by spray pyrolysis10.1016/j.ceramint.2016.03.110 ↗
33. Effect of lithium doping on microstructural and optical properties of ZnO nanocrystalline films prepared by sol-gel method10.3390/cryst8050228 ↗
34. X-ray determination of crystallite size and effect of lattice strain on debye-waller factors of platinum nano powder10.1007/s12034-013-0553-1 ↗
35. Dielectric properties of ErFeO3 ceramics over a broad temperature range10.1016/j.jallcom.2014.08.026 ↗
36. Tunable band gaps of Co3-xCuxO4 nanorods with various Cu doping concentrations10.1039/C4RA01463D ↗
37. Crystal field splitting and optical bandgap of hexagonal LuFeO3 films10.1063/1.4771601 ↗
38. Optical properties and electronic structure of multiferroic hexagonal orthoferrites RFeO3 (r= Ho, Er, Lu)10.1063/1.3693588 ↗
39. Modified tauc–Lorentz dispersion model leading to a more accurate representation of absorption features below the bandgap10.1016/j.tsf.2015.07.035 ↗
40. Direct band gaps in multiferroic h-LuFeO310.1063/1.4908246 ↗
41. Optical spectroscopy: an effective tool to probe the origin of dielectric loss in Cr doped PrFeO310.1016/j.ceramint.2019.01.177 ↗
42. Determination of refractive index and correction to effective electron mass in PbTe and PbSe10.1088/0370-1328/81/3/319 ↗
43. Moss · 1973
44. High-temperature colossal dielectric response in RFeO3 (r=la, Pr and Sm) ceramics10.1016/j.ceramint.2014.08.124 ↗
45. Dielectric relaxation in LuFeO3 ceramics10.1016/j.ssc.2009.05.036 ↗
46. Magnetic and electrical properties of in doped cobalt ferrite nanoparticles10.1063/1.4759436 ↗
47. Structural characteristics and dielectric properties of La1-xCoxFeO3 and LaFe1-xCoxO3 synthesized via metal organic complexes10.1016/j.egypro.2013.06.815 ↗
48. Hodgson · 1970
49. Analysis of the semiconducting properties of cobalt ferrite10.1016/0022-3697(59)90206-9 ↗