Process limitation for p-type CuSbS2 semiconductor with high electrical mobility of 20cm2V−1s−1

Abstract CuSbS 2 bulks have been prepared by reactive sintering the mixture of CuS and Sb 2 S 3 at 350, 375, 400, 450, and 500 °C for 2 h and at the sintering temperature of 400 °C for 0.5, 1, 2, and 3 h under a compensation disc of CuS for atmospheric control. Composition, Structure, morphology, and electrical properties of the sintered bulks were analyzed. The compositions of Cu, Sb and S did not change until the temperature reached at and above 450 °C. The highest electrical conductivity of 15 S cm −1 and the highest mobility of 20 cm 2 V −1 s −1 were achieved for CuSbS 2 sintered at 400 °C for 2 h. 5% deviations in the Cu/Sb and S/(Cu + Sb) rations caused a serious problem in the degradation of electrical properties, though the CuSbS 2 remained as a single phase. Therefore, CuSbS 2 is the semiconductor needs to have a controlled composition.