journal article·2014-12

Investigation into the optoelectrical properties of tungsten oxide thin films annealed in an oxygen air

A. Arfaoui, B. Ouni, S. Touihri, T. Mannoubi

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Abstract

Abstract Tungsten oxide (WO x ) thin film have been deposited onto glass substrates using the thermal vacuum evaporation technique, monitored by an annealing process in a variable oxygen atmosphere. Analysis by X-ray diffraction and Raman spectroscopy showed the structural changes from orthorhombic to monoclinic which depend on the annealing temperature and the oxygen content. AFM study shows that the increase of oxygen content leads to a decrease of the root-mean-square from 94.64 nm to 2 nm. Ellipsometric measurements have been used to evaluate the optical constants. Further, it is found that when the oxygen content increases, the band gap of the annealed layer varies from 3.01 eV to 3.52 eV by against, the Urbach energy decreases. The AC conductivity plot showed a universal power law according to the Jonscher model. Moreover, at high frequency semiconductor-to-metallic behavior has been observed. Finally, the effect of annealing in oxygen atmosphere on their structural modifications, morphological, optical properties and electrical conductivity are reported.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · Gas Sensing Nanomaterials and Sensors · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (59)

Show source-provided references
1. Tungsten oxide/PEDOT:PSS hybrid cascade hole extraction layer for polymer solar cells with enhanced long-term stability and power conversion efficiency10.1016/j.solmat.2013.11.007 ↗
2. Hot-wire vapor deposited tungsten and molybdenum oxide films used for carrier injection/transport in organic optoelectronic devices10.1016/j.mssp.2013.02.006 ↗
3. Preparation and characterization of MoO3 hole-injection layer for organic solar cell fabrication and optimization10.1016/j.solmat.2013.10.002 ↗
4. Inverted structure organic photovoltaic devices employing a low temperature solution processed WO3 anode buffer layer10.1016/j.orgel.2012.06.045 ↗
5. Electrodeposited NiO anode interlayers: enhancement of the charge carrier selectivity in organic solar cells10.1016/j.solmat.2013.07.020 ↗
6. Nanostructure effect of V2O5 buffer layer on performance of polymer-fullerene devices10.1016/j.orgel.2011.10.006 ↗
7. Characterization and photocatalytic properties of hexagonal and monoclinic WO3 prepared via microwave-assisted hydrothermal synthesis
8. Vacuum deposited WO3 thin films based sub-ppm H2S sensor10.1016/j.matchemphys.2012.03.080 ↗
9. Implementation of Ag nanoparticle incorporated WO3 thin film photoanode for hydrogen production10.1016/j.ijhydene.2012.11.132 ↗
10. Electrochromic WO3 thin films active in the IR region10.1016/j.solmat.2007.01.025 ↗
11. Photoresponse and H2 production of topographically controlled PEG assisted Sol-gel WO3 nanocrystalline thin films10.1016/j.ijhydene.2011.07.129 ↗
12. Hot-wire chemical vapor deposition of WO3−x thin films of various oxygen10.1016/j.matchemphys.2013.02.072 ↗
13. Electrochromism in surface modified crystalline WO3 thin films grown by reactive DC magnetron sputtering10.1016/j.apsusc.2013.05.051 ↗
14. Influence of annealing temperature on nanostructured thin films of tungsten trioxide10.1016/j.mssp.2013.07.018 ↗
15. Study of structural and optical properties of sprayed WO3 thin films using enhanced characterization techniques along with the Boubaker polynomials expansion scheme (BPES)10.1016/j.jallcom.2009.07.103 ↗
16. Growth, structural, electrical and optical properties of the thermally evaporated tungsten trioxide (WO3) thin film10.1016/j.matchemphys.2008.09.071 ↗
17. Structure and properties of WO3 thin films for electrochromic devices application
18. Electrochromism and reversible changes in the position of fundamental absorption edge in cathodically deposited amorphous WO310.1016/j.electacta.2004.01.020 ↗
19. Transport properties and charge density wave instabilities in the quasi-two-dimensional monophosphate tungsten bronzes (PO2)4(WO3)2m (m=5) and KxP4W8O3210.1016/S1293-2558(01)01265-1 ↗
20. Structural study of thin films prepared from tungstate glass matrix by Raman and X-ray absorption spectroscopy10.1016/j.apsusc.2008.02.107 ↗
21. Effect of crystallinity on electrochromic mechanism of Lix WO3 thin films10.1016/S0167-2738(02)00732-4 ↗
22. Evolution of the conducting state of polyaniline from localized to mesocopic metallic to intrinsic metallic regimes10.1016/0379-6779(94)02438-5 ↗
23. Highly sensitive and selective gas sensors using p-type oxide semiconductors: overview10.1016/j.snb.2013.11.005 ↗
24. Annealing effect on optical parameters of Se85−xTe15Hgx thin films10.1016/j.jallcom.2013.04.025 ↗
25. Solar water oxidation in sputter-deposited nanocrystalline WO3photoanodes via tuning of Ar:O2 flow rate combinations10.1016/j.matchemphys.2013.11.018 ↗
26. Anion vacancies as a source of persistent photoconductivity in II–VI and chalcopyrite semiconductors10.1103/PhysRevB.72.035215 ↗
27. On the origin of intrinsic donors in ZnO10.1016/j.apsusc.2009.12.040 ↗
28. Growth and induced color centers in YAlO3–Nd single crystals10.1002/1521-396X(200103)184:1<239::AID-PSSA239>3.0.CO;2-I ↗
29. Ab initio study of oxygen point defects on tungsten trioxide surfaces10.1016/j.susc.2011.08.018 ↗
30. Synthesis and characterization of WO3 spherical nanoparticles and nanorods10.1016/j.materresbull.2013.08.028 ↗
31. One-step facile electrochemical preparation of WO3/graphene nanocomposites with improved electrochromic properties10.1016/j.electacta.2013.11.123 ↗
32. Physical properties characterization of WO3 films grown by hot-filament metal oxide deposition10.1016/j.mseb.2010.03.061 ↗
33. Optical and electrical properties of N-doped ZnO heterojunction photodiode10.1016/j.physe.2013.10.038 ↗
34. Inverted structure organic photovoltaic devices employing a low temperature solution processed WO3 anode buffer layer10.1016/j.orgel.2012.06.045 ↗
35. Optical properties of thin CVD-tungsten oxide flms by spectroscopic ellipsometry10.1016/S0022-0248(98)00993-2 ↗
36. Spectroscopic ellipsometry characterization of electrochromic tungsten oxide and nickel oxide thin films made by sputter deposition10.1016/j.solmat.2009.12.011 ↗
37. Fujiwara · 2007
38. Structural and optical properties of WO3 sputtered thin films nanostructured by laser interference lithography10.1016/j.apsusc.2013.03.072 ↗
39. Structural and optical properties of WO3 films deposited by pulsed laser deposition10.1016/j.jallcom.2013.08.166 ↗
40. Physical properties and surface/interface analysis of nanocrystalline WO3 films grown under variable oxygen gas flow rates10.1016/j.apsusc.2012.07.014 ↗
41. Chemical trends for localized gap states in amorphous semiconductors10.1016/0038-1098(78)90155-2 ↗
42. Investigation of electrical and dielectric properties of antimony oxide (Sb2O4) semiconductor thin films for TCO and optoelectronic applications10.1016/j.jnoncrysol.2013.02.006 ↗
43. Oxygen-vacancy-related dielectric relaxations in Na0.5K0.5NbO310.1016/j.ssc.2013.11.008 ↗
44. Modeling the optical properties of WO3 and WO3–SiO2 thin films10.1016/j.solmat.2008.01.021 ↗
45. DC and AC characterizations of WO3 sensors under ethanol vapors10.1016/j.snb.2005.12.036 ↗
46. AC conductivity and dielectric properties of bulk tungsten trioxide (WO3)10.1016/j.physb.2012.07.043 ↗
47. The role of surface oxygen vacancies upon WO3 conductivity10.1016/S0039-6028(03)00477-1 ↗
48. Structural, electrical transport and NO2 sensing properties of Y-doped ZnO thin films10.1016/j.jallcom.2012.04.104 ↗
49. Electrical conductivity and dielectric relaxation in non-crystalline films of tungsten trioxide10.1016/j.jnoncrysol.2007.06.042 ↗
50. The universal dielectric response10.1038/267673a0 ↗
51. The structure and electrical conductivity of vacuum-annealed WO3 thin films10.1016/j.tsf.2004.04.018 ↗
52. AC conductivity and dielectric properties of Sb2S3 films10.1016/S0042-207X(00)00403-6 ↗
53. Effect of oxygen content on the transport properties of La-doped SrTiO3 thin films10.1016/j.ssc.2008.09.030 ↗
54. Transport properties and conduction mechanisms in CuFe2O4 and Cu1−xZnxGa0.3Fe1.7O4 compounds10.1016/j.physb.2009.04.044 ↗
55. Conduction in non-crystalline materials. III. Localized states in a pseudogap and near extremities of conduction and valence bands10.1080/14786436908216338 ↗
56. Oxygen-vacancy-related dielectric relaxations in Na0.5K0.5NbO310.1016/j.ssc.2013.11.008 ↗
57. Grain growth control in NaNbO3–SrTiO3 ceramics by mechanosynthesis and spark plasma sintering10.1111/j.1551-2916.2007.01695.x ↗
58. Ferroelectric and dielectric properties of bismuth neodymium titanate ceramics prepared using sol–gel derived fine powders10.1016/j.physleta.2005.07.063 ↗
59. Mechanism of NOx sensing on WO3 surface: first principale calculations10.1016/j.apsusc.2013.12.095 ↗