journal article·2018-12

Lead free, air stable perovskite derivative Cs2SnI6 as HTM in DSSCs employing TiO2 nanotubes as photoanode

Lekha Peedikakkandy, Johns Naduvath, Sudhanshu Mallick, Parag Bhargava

Publisher page

Abstract

Abstract Cs2SnI6 is an air-stable and non-toxic perovskite variant photovoltaic material which exhibits p-type conductivity under doped conditions. In this work, we report the synthesis and stability studies of Cs2SnI6 towards its application as a solid-state Hole Transport Material (HTM) in Titania Nanotube (TNT) based Dye Sensitized Solar Cells (DSSCs). Cs2SnI6 crystals were synthesized using precipitation method and its stability was assessed using X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS) and Thermogravimetric Analysis (TGA). Cs2SnI6 doped with SnI2 was deposited onto the TNT photo-anode as the HTM layer through dip coating. Deposition time was varied to obtain a continuous layer of Cs2SnI6 HTM over TNT photo-anode and cell characteristics were studied. We were able to fabricate air stable, all solid-state solar cells with a Jsc of 6 mA/cm2, Voc of 536 mV and PCE of 1.3%. The study propounds contemporary analysis on Sn based perovskite systems, in the field of DSSCs.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Perovskite Materials and Applications · Chalcogenide Semiconductor Thin Films · Quantum Dots Synthesis And Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. The emergence of perovskite solar cells10.1038/nphoton.2014.134 ↗
2. Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%10.1038/srep00591 ↗
3. Organic–inorganic perovskites: structural versatility for functional materials design10.1021/acs.chemrev.5b00715 ↗
4. Recent advances in perovskite solar cells: efficiency, stability and lead-free perovskite10.1039/C7TA00366H ↗
5. Iodide management in formamidinium-lead-halide–based perovskite layers for efficient solar cells10.1126/science.aan2301 ↗
6. Influence of metal substitution on hybrid halide perovskites: towards lead-free perovskite solar cells10.1039/C7TA09943F ↗
7. Lead-free solid-state organic-inorganic halide perovskite solar cells10.1038/nphoton.2014.82 ↗
8. Rational design: a high-throughput computational screening and experimental validation methodology for lead-free and emergent hybrid perovskites10.1021/acsenergylett.7b00035 ↗
9. New class of lead free perovskite material for low-cost solar cell application10.1016/j.materresbull.2017.09.054 ↗
10. CsSnI3: semiconductor or metal? High electrical conductivity and strong near-infrared photoluminescence from a single material. High hole mobility and phase-transitions10.1021/ja301539s ↗
11. Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals10.1021/jacs.5b13470 ↗
12. Investigation of cesium tin/lead iodide (CsSn1−xPbxI3) systems10.1016/j.materresbull.2016.08.052 ↗
13. Solid state plasmonic dye sensitized solar cells based on solution processed perovskite CsSnI3 as the hole transporter10.1039/C4RA09719J ↗
14. Recrystallization and phase stability study of cesium tin iodide for application as a hole transporter in dye sensitized solar cells10.1016/j.mssp.2015.01.023 ↗
15. From unstable CsSnI3 to air-stable Cs2SnI6: a lead-free perovskite solar cell light absorber with bandgap of 1.48 eV and high absorption coefficient10.1016/j.solmat.2016.09.022 ↗
16. Air-stable molecular semiconducting iodosalts for solar cell applications: Cs2SnI6 as a hole conductor10.1021/ja508464w ↗
17. Investigation of interfacial charge transfer in solution processed Cs2SnI6 thin films10.1021/acs.jpcc.7b04019 ↗
18. Intrinsic defects in a photovoltaic perovskite variant Cs2SnI610.1039/C5CP03102H ↗
19. Mixed-halide Cs2SnI3Br3 perovskite as low resistance hole-transporting material in dye-sensitized solar cells10.1016/j.electacta.2015.10.030 ↗
20. Stress tests on dye-sensitized solar cells with the Cs2SnI6 defect perovskite as hole-transporting material10.1016/j.egypro.2016.11.317 ↗
21. High-performance large-scale flexible dye-sensitized solar cells based on anodic TiO2 nanotube arrays10.1021/am402687j ↗
22. Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays10.1021/nl062000o ↗
23. Enhancing the efficiency of quasi-solid-state dye-sensitized solar cells by adding bis(trifluoromethane)sulfonimide lithium salt and camphorsulfonic acid to gel-based electrolytes10.1016/j.materresbull.2018.07.017 ↗
24. Bipyridine type Co-complexes as hole-transporting material dopants in perovskite solar cells10.1039/C5RA25753K ↗
25. A new type of transparent and low cost counter-electrode based on platinum nanoparticles for dye-sensitized solar cells10.1039/c0ee00463d ↗