journal article·2017-04

Synthesis, structure, and luminescence properties of a novel double-perovskite Sr 2 LaNbO 6 :Mn 4+ phosphor

Anjie Fu, Anxiang Guan, Dongyan Yu, Siyu Xia, Fangfang Gao, Xiaoshan Zhang, Liya Zhou, Yinghao Li, Rongguan Li

Publisher page

Abstract

Abstract A novel phosphor, Sr 2 LaNbO 6 :Mn 4+ , is synthesized by conventional solid-state reaction. The phosphor can be excited at 300–500 nm and emit a deep-red light. An emission band peak of 694 nm is observed from the spin-forbidden transition 2 E → 4 A 2 of Mn 4+ ions. Energy transfer between the Mn 4+ –Mn 4+ pairs decreases fluorescence decay time from 0.815 ms to 0.512 ms. The resistance of luminescence against thermal impact is also investigated by emission spectroscopy at heating temperatures from 300 K to 500 K. The calculated activation energy Δ E (∼0.345 eV) demonstrate good thermal stability of the phosphors. All these results indicate that the phosphor can be applied in white-light-emitting diodes.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Perovskite Materials and Applications · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (40)

Show source-provided references
1. Deep red phosphors SrAl12O19:Mn4+, M (M=Li+, Na+, K+, Mg2+) for high colour rendering white LEDs10.1002/pssa.201228815 ↗
2. Site occupancy preference, enhancement mechanism, and thermal resistance of Mn4+ red luminescence in Sr4Al14O25:Mn4+ for warm WLEDs10.1021/acs.chemmater.5b00226 ↗
3. How to produce white light in a single-phase host
4. Some misconceptions concerning the electronic spectra of tri-positive europium and cerium10.1039/c3cs60033e ↗
5. A new-generation color converter for high-power white LED: transparent Ce3+:YAG phosphor-in-glass10.1002/lpor.201300140 ↗
6. CaMg2 Al16 O27:Mn4+-based red phosphor: a potential color converter for high-powered warm W-LED10.1021/am507316b ↗
7. Chen · 2010
8. Citric based sol–gel synthesis and luminescence characteristics of CaLa2ZnO5:Eu3+ phosphors for blue LED excited white LEDs10.1016/j.jallcom.2011.09.078 ↗
9. A host sensitized reddish-orange Gd2 MoO6:Sm3+ phosphor for light emitting diodes10.1063/1.3557065 ↗
10. Luminescence properties, energy transfer and multisite luminescence of Bi3+/Sm3+/Eu3+-coactivated Ca20 Al26 Mg3Si3 O68 as a potential phosphor for white-light LEDs10.1039/C6RA17303A ↗
11. Synthesis and luminescence properties of CaAl2O4:Mn4+ phosphor10.1016/j.optmat.2014.10.002 ↗
12. Deep red phosphors SrMgAl10O17:Mn4+, m (M=Li+, Na+, K+, Cl-) for warm white light emitting diodes10.1007/s10854-014-1928-9 ↗
13. A deep red phosphor Li2MgTiO4:Mn4+ exhibiting abnormal emission: potential application as color converter for warm w-LEDs10.1016/j.cej.2015.12.027 ↗
14. Luminescence properties of double-perovskite Sr2 Ca1-2xEuxNaxMoO6 red-emitting phosphors prepared by the citric acid-assisted sol?gel method10.1007/s10853-009-4123-2 ↗
15. Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu Li for white light UVLED applications10.1007/s00340-008-3028-0 ↗
16. A double-perovskite Sr2 ZnWO6:Mn4+ deep red phosphor: synthesis and luminescence properties10.1016/j.ceramint.2016.07.173 ↗
17. A reddish orange stoichiometric phosphor LiEu(PO3)4 for white light-emitting diodes10.1016/j.ceramint.2013.10.095 ↗
18. Novel single-phase white-emitting phosphor Sr6Gd2Na2(PO4)6 F2:Eu2+,Mn2+: band gap, luminescence, and energy transfer
19. Ab initio and crystal field studies of the Mn4+-doped Ba2 LaNbO6 double-perovskite10.1016/j.jlumin.2011.09.017 ↗
20. Persistent luminescence mechanisms: human imagination at work10.1364/OME.2.000371 ↗
21. CaMg2Al16O27:Mn4+-based red phosphor: a potential color converter for high-powered warm W-LED10.1021/am507316b ↗
22. A novel blue luminescent material Sr6Ca4(PO4)6 F2:Eu2+, W. Zhang10.1016/j.materresbull.2015.07.031 ↗
23. Low temperature synthesis and photoluminescence properties of red emitting Mg2 SiO4:Eu3+ nanophosphor for near UV light emitting diodes10.1016/j.snb.2014.01.018 ↗
24. Luminescence and EPR investigations of Mn activated calcium aluminate prepared via combustion method10.1016/j.optmat.2007.01.003 ↗
25. A high color purity deep red emitting phosphor SrGe4O9:Mn4+ for warm white LEDs10.1016/j.powtec.2016.01.017 ↗
26. Chemical trends of Mn4+ emission in solids10.1039/C4TC00031E ↗
27. Energy transfer in oxidic phosphors
28. Characterization of energy transfer interactions between rare earth ions10.1149/1.2424184 ↗
29. Regulated morphology/phase structure and enhanced fluorescence in YF3:Eu3+,Bi3+ via a facile method10.1039/C5CE01049G ↗
30. Multicolor tunable luminescence and paramagnetic properties of NaGdF4:Tb3+/Sm3+ multifunctional nanomaterials10.1039/c4dt00158c ↗
31. A novel double-perovskite Gd2ZnTiO6:Mn4+ red phosphor for UV-based w-LEDs: structure and luminescence properties10.1039/C6TC00313C ↗
32. Synthesis and luminescence properties of novel red phosphors LiRGe2O6:Mn4+ (R=Al or Ga)10.1016/j.jallcom.2015.07.080 ↗
33. The electronic spectrum of cesium hexafluoromanganese(IV)10.1016/0022-2852(71)90270-0 ↗
34. Electronic energy levels of the Mn4+ ion in the perovskite, CaZrO310.1149/2.020307jss ↗
35. Influence of covalency on the Mn4+2Eg→4A2g emission energy in crystals10.1149/2.0031503jss ↗
36. Chen · 2010
37. Ab initio and crystal field studies of the Mn4+-doped Ba2 LaNbO6 double-perovskite10.1016/j.jlumin.2011.09.017 ↗
38. A novel efficient Mn(4 + ) activated Ca14Al10Zn6O35 phosphor: application in red-emitting and white LEDs10.1021/ic501641q ↗
39. Synthesis and photoluminescence spectroscopy of BaGeF6:Mn4+ red phosphor10.1016/j.optmat.2015.01.039 ↗
40. Li3Mg2NbO6:Mn4+ red phosphor for light-emitting diode: synthesis and luminescence properties10.1016/j.optmat.2016.04.041 ↗