journal article·2026-04Open access

Photoenhanced supercapacitance in fractal silicon nanowire-based arrays

Maurilio Galletta, Francesco Nastasi, Francesco Priolo, Antonio A. Leonardi, Alessia Irrera

Materials Letters· Volume 408

Abstract

Sustainable energy technologies necessitate efficient and reliable energy-storage systems complementing renewable energy generation. Supercapacitors offer superior power density and cycling stability, making them indispensable for high-power applications. Silicon, the cornerstone of microelectronics, is an earth-abundant material whose nanostructured forms, particularly silicon nanowires (SiNWs), exhibit promising electrochemical and optoelectronic properties. Here we report the fabrication and characterization of fractal and quantum confined SiNW-based supercapacitors exhibiting a fourfold enhancement in specific capacitance under simulated solar illumination. Electrochemical measurements reveal typical non-faradic behavior, with specific capacitance increasing from ≈300 μF/cm 2 in the dark to ≈1.2 mF/cm 2 under illumination. The results highlight the potential of SiNWs as photocapacitors for next-generation electrochemical energy-storage devices.
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Research context

OpenAlex topics: Nanowire Synthesis and Applications · Carbon Nanotubes in Composites · Graphene research and applications

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References (16)

Show source-provided references
1. Renewable energy intermittency mitigation in microgrids: state-of-the-art and future prospects, proceedings of 2020 4th international conference on green energy and applications
2. Supercapacitors outperform conventional batteries [energy and security]10.1109/MCE.2018.2835958 ↗
3. Silicon electrodeposition for microelectronics and distributed energy: a Mini-review10.3390/electrochem3040050 ↗
4. Hybrid light harvesting antenna based on Si NWs and RuOs2 Dendrons for near IR light-emission10.1021/acsomega.5c02574 ↗
5. A novel silicon platform for selective isolation, quantification, and molecular analysis of small extracellular vesicles10.2147/IJN.S310896 ↗
6. Microscale silicon-based anodes: fundamental understanding and industrial prospects for practical high-energy Lithium-ion batteries10.1021/acsnano.1c05898 ↗
7. Luminescent silicon nanowires as novel sensor for environmental air quality control10.3390/s22228755 ↗
8. 2D fractal arrays of ultrathin silicon nanowires as cost-effective and high-performance substrate for supercapacitors10.1002/aesr.202400080 ↗
9. Cost-effective fabrication of fractal silicon nanowire arrays10.3390/nano11081972 ↗
10. Pt nanoclusters on GaN nanowires for solar-asssisted seawater hydrogen evolution10.1038/s41467-023-35782-z ↗
11. Recent advances in photo-supercapacitor: a Mini review, advanced
12. Enhancing the specific capacitance of a porous silicon-based capacitor by embedding graphene combined with three-dimensional electrochemical etching10.1016/j.elecom.2023.107555 ↗
13. Activated carbon electrode with promising specific capacitance based on potassium bromide redox additive electrolyte for supercapacitor application10.1016/j.jmrt.2021.01.080 ↗
14. Capacitance enhancement in a semiconductor nanostructure-based supercapacitor by solar light and a self-powered supercapacitor–photodetector system10.1002/adfm.201601260 ↗
15. Study of RuO2- and MnO2-based electrode materials and their performance review in conjunction with PANi for supercapacitor applications10.1007/s11581-024-05828-3 ↗
16. Assessment of wafer-level transfer techniques of graphene with respect to semiconductor industry requirements10.1002/admt.202201587 ↗