journal article·2024-10Open access

Hybrid Cu sinter paste for low temperature bonding of bare semiconductors

Gordon Elger, Sri Krishna Bhogaraju, Martin Schneider-Ramelow

Materials Letters· Volume 372

Abstract

A novel hybrid copper paste was developed for low temperature sintering of bare semiconductors. Cu(II) formate (Cu(for)) is complexed in amino-2-propanol (A2P) and added to a paste of etched brass micro flakes. A two-step sintering process is applied: The paste is printed and dried at 120 °C under formic acid (FA) enriched N2 atmosphere (FAN2) for 5 min. Afterwards, bare semiconductors are placed and sintered at 250 °C for 5 min applying a bonding pressure of 20 MPa/10 MPa. By the thermal decomposition of the Cu(for) atomic Cu is released and forms in-situ Cu-nanoparticles. An interconnect is realized with shear strength >100 MPa.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: 3D IC and TSV technologies · Electronic Packaging and Soldering Technologies · Nanomaterials and Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (12)

Show source-provided references
1. H. Zhang, N. Lee, High temperature lead-free bonding materials – the need, the Potential Candidates and the Challenges, in: Lead‐free Soldering Process Development and Reliability, edited by Bath, J., 2020, pp. 155–189. https://doi.org/10.1002/9781119482093.ch6.10.1002/9781119482093.ch6 ↗
2. Identifying the development state of sintered silver (-Ag) as a bonding material in the microelectronic packaging via a patent landscape study10.1115/1.4033069 ↗
3. D. Ishikawa, B. Ngoc An, M. Mail, H. Wurst, B. Leyrer, T. Blank, M. Weber, H. Nakako, Bonding abilities of pressure-assisted sintered copper for die-bonding of large chips, Trans. Japan Inst. Electron. Packag. 13 (2020) E20-003-1-E20003-3.10.5104/jiepeng.13.E20-003-1 ↗
4. Low cost copper based sintered interconnect material for optoelectronics packaging
5. Comparing the mechanical and thermal-electrical properties of sintered copper (Cu) and sintered silver (Ag) joints10.1016/j.jallcom.2021.158783 ↗
6. The rise of conductive copper inks: challenges and perspectives
7. S.K. Bhogaraju, F. Conti, G. Elger, Copper die bonding using copper formate based pastes with α-terpineol, amino-2-propanol and hexylamine as binders. In: 2020 IEEE 8th Electronics System-Integration Technology Conference (ESTC)10.1109/ESTC48849.2020.9229801 ↗
8. IEEE, 2020, pp 1-7. https://doi.org/10.1109/ESTC48849.2020.9229801.10.1109/ESTC48849.2020.9229801 ↗
9. A self-reducible and alcohol-soluble copper-based metal-organic decomposition ink for printed electronics10.1021/am4036306 ↗
10. Decomposition mechanism and morphological evolution of in situ realized Cu nanoparticles in Cu complex inks
11. Die-attach bonding with etched micro brass metal pigment flakes for high-power electronics packaging10.1021/acsaelm.1c00721 ↗
12. Thermodynamics of Sintering