journal article·2024-08-07

Enhanced Performance of Laser-Induced Graphene Supercapacitors via Integration with Candle-Soot Nanoparticles

Arnab Ghosh, Sukhman Kaur, Gulshan Verma, Christian Dolle, Raheleh Azmi, Stefan Heissler, Yolita M. Eggeler, Kunal Mondal, Dario Mager, Ankur Gupta, Jan G. Korvink, De-Yi Wang, Ashutosh Sharma, Monsur Islam

ACS Applied Materials & Interfaces· Volume 16· Issue 31
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Abstract

Laser-induced graphene (LIG) has been emerging as a promising electrode material for supercapacitors due to its cost-effective and straightforward fabrication approach. However, LIG-based supercapacitors still face challenges with limited capacitance and stability. To overcome these limitations, in this work, we present a novel, cost-effective, and facile fabrication approach by integrating LIG materials with candle-soot nanoparticles. The composite electrode is fabricated by laser irradiation on a Kapton sheet to generate LIG material, followed by spray-coating with candle-soot nanoparticles and annealing. Materials characterization reveals that the annealing process enables a robust connection between the nanoparticles and the LIG materials and enhances nanoparticle graphitization. The prepared supercapacitor yields a maximum specific capacitance of 15.1 mF/cm 2 at 0.1 mA/cm 2, with a maximum energy density of 2.1 μWh/cm 2 and a power density of 50 μW/cm 2 . Notably, the synergistic activity of candle soot and LIG surpasses the performances of previously reported LIG-based supercapacitors. Furthermore, the cyclic stability of the device demonstrates excellent capacitance retention of 80% and Coulombic efficiency of 100% over 10000 cycles.
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Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Graphene research and applications · Laser-Ablation Synthesis of Nanoparticles

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

IMDEA Materials Institute, Tecnogetafe, Calle Eric Kandel, 2, 28906 Getafe, Madrid Spain

Mechanical Engineering Department, Punjab Engineering College, Sector 12, Chandigarh, 160012, India

Department of Mechanical Engineering, Indian Institute of Technology Jodhpur, Jodhpur, Rajasthan 342030, India

Microscopy of Nanoscale Structures and Mechanisms (MNM), Laboratory for Electron Microscopy (LEM), Karlsruhe Institute of Technology, Engesserstr. 7, D-76131 Karlsruhe, Germany

Institut für Angewandte Materialien, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Institut für Funktionelle Grenzflächen, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Idaho National Laboratory, 1955 North Fremont Avenue, Idaho Falls, Idaho 83415, United States

Institute of Microstructure Technology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Department of Chemical Engineering, Indian Institute of Technology, Kanpur, 208016, Uttar Pradesh, India

Funding

Deutsche Forschungsgemeinschaft

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