DataVXACS Applied Materials & InterfacesPaper
journal article·2023-01-11

Engineering Catalysis within a Saturated In(III)-Based MOF Possessing Dynamic Ligand–Metal Bonding

Ricardo A. Peralta, Michael T. Huxley, Pengbo Lyu, Mariana L. Díaz-Ramírez, Sun Ho Park, Juan L. Obeso, Carolina Leyva, Cheol Yeong Heo, Sejin Jang, Ja Hun Kwak, Guillaume Maurin, Ilich A. Ibarra, Nak Cheon Jeong

ACS Applied Materials & Interfaces· Volume 15· Issue 1
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Source abstract

Abstract

Metal-organic frameworks have developed into a formidable heterogeneous catalysis platform in recent years. It is well established that thermolysis of coordinated solvents from MOF nodes can render highly reactive, coordinatively unsaturated metal complexes which are stabilized via site isolation and serve as active sites in catalysis. Such approaches are limited to frameworks featuring solvated transition-metal complexes and must be stable toward the formation of "permanent" open metal sites. Herein, we exploit the hemilability of metal-carboxylate bonds to generate transient open metal sites in an In(III) MOF, pertinent to In-centered catalysis. The transient open metal sites catalyze the Strecker reaction over multiple cycles without loss of activity or crystallinity. We employ computational and spectroscopic methods to confirm the formation of open metal sites via transient dissociation of In(III)-carboxylate bonds. Furthermore, the amount of transient open metal sites within the material and thus the catalytic performance can be temperature-modulated.
Source: openalex_inverted_index · Quality: baseline

Research context

Catalysis & surfaces

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Magnetism in coordination complexes · Polyoxometalates: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Química, División de Ciencias Básicas e Ingeniería, UAM-I, Ciudad de Mexico 09340, México

Department of Chemistry and Centre for Advanced Nanomaterials, The University of Adelaide, Adelaide, South Australia 5005, Australia

Hunan Provincial Key Laboratory of Thin Film Materials and Devices, School of Material Sciences and Engineering, Xiangtan University, Xiangtan 411105, China

ICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier 34095, France

Department of Physics & Chemistry, Center for Basic Science, DGIST, Daegu 42988, Korea

Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán, 04510 Ciudad de México, México

Instituto Politécnico Nacional, CICATA U. Legaria 694, Irrigación, Miguel Hidalgo, 11500 Ciudad de México, México

Department of Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Korea

Funding

Universidad Nacional Aut?noma de M?xico · National Research Foundation

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