DataVXACS Applied Materials & InterfacesPaper
journal article·2020-09-16Open access

Functionalized NU-1000 with an Iridium Organometallic Fragment: SO2 Capture Enhancement

Saidulu Gorla, Mariana L. Díaz-Ramírez, Niroshani S. Abeynayake, David M. Kaphan, Daryl R. Williams, Vladimir Martis, Hugo A. Lara-García, Bruno Donnadieu, Nazario Lopez, Ilich A. Ibarra, Virginia Montiel-Palma

ACS Applied Materials & Interfaces· Volume 12· Issue 37
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Source abstract

Abstract

A new material, MOF-type [Ir]@NU-1000, was accessed from the incorporation of the iridium organometallic fragment [Ir{κ3(P,Si,Si)PhP(o-C6H4CH2SiiPr2)2}] into NU-1000. The new material incorporates less than 1 wt % of Ir(III) (molar ratio Ir to NU-1000, 1:11), but the heat of adsorption for SO2 is significantly enhanced with respect to that of NU-1000. Being a highly promising adsorbent for SO2 capture, [Ir]@NU-1000 combines exceptional SO2 uptake at room temperature and outstanding cyclability. Additionally, it is stable and can be regenerated after SO2 desorption at low temperature.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Industrial Gas Emission Control · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry, Mississippi State University, P.O. Box 9573, Mississippi State, Mississippi 39762, United States

Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Coyoacán 04510, Ciudad de México, Mexico

Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States

Surfaces and Particle Engineering Laboratory (SPEL), Department of Chemical Engineering, Imperial College London, South Kensington Campus, London SW7 2AZ, U.K.

Surface Measurement Systems, Unit 5, Wharfside, Rosemont Road, London HA0 4PE, U.K.

Instituto de Física, Universidad Nacional Autónoma de México, Circuito de la Investigación Científica s/n, CU, Coyoacán 04510, Ciudad de México, Mexico

Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, Cuernavaca, Morelos 62209, Mexico

Funding

Basic Energy Sciences · Mississippi State University · Universidad Nacional Aut?noma de M?xico · Consejo Nacional de Ciencia y Tecnolog?a

References (60)

Show source-provided references
1. 10.1080/15287394.2016.115354810.1080/15287394.2016.1153548 ↗
2. 10.1164/ajrccm/145.3.60010.1164/ajrccm/145.3.600 ↗
3. 10.1088/1748-9326/8/1/01400310.1088/1748-9326/8/1/014003 ↗
4. 10.1016/j.fuel.2014.12.06510.1016/j.fuel.2014.12.065 ↗
5. 10.3155/1047-3289.59.6.72510.3155/1047-3289.59.6.725 ↗
6. 10.1016/j.cplett.2013.05.06010.1016/j.cplett.2013.05.060 ↗
7. 10.1021/jp027398110.1021/jp0273981 ↗
8. 10.1002/ceat.20060036010.1002/ceat.200600360 ↗
9. 10.1260/0263-6174.29.4.41310.1260/0263-6174.29.4.413 ↗
10. 10.1016/j.jhazmat.2013.09.01410.1016/j.jhazmat.2013.09.014 ↗
11. 10.1021/cm000294n10.1021/cm000294n ↗
12. 10.1021/la026424j10.1021/la026424j ↗
13. 10.1039/b212025a10.1039/b212025a ↗
14. 10.1039/C0DT00975J10.1039/C0DT00975J ↗
15. 10.1021/ic50037a01710.1021/ic50037a017 ↗
16. 10.1021/ja00958a05510.1021/ja00958a055 ↗
17. 10.1021/om00013a02410.1021/om00013a024 ↗
18. 10.1021/om00011a07210.1021/om00011a072 ↗
19. 10.1016/S0022-328X(00)90582-510.1016/S0022-328X(00)90582-5 ↗
20. 10.1073/pnas.080490010510.1073/pnas.0804900105 ↗
21. 10.1016/j.micromeso.2013.02.00210.1016/j.micromeso.2013.02.002 ↗
22. 10.1021/jacs.8b1152510.1021/jacs.8b11525 ↗
23. 10.1021/acscentsci.6b0029010.1021/acscentsci.6b00290 ↗
24. 10.1021/jacs.5b1251510.1021/jacs.5b12515 ↗
25. 10.1021/jacs.7b0293610.1021/jacs.7b02936 ↗
26. 10.1039/C4CS00076E10.1039/C4CS00076E ↗
27. 10.1038/s41929-018-0069-610.1038/s41929-018-0069-6 ↗
28. 10.1021/acs.chemmater.6b0324410.1021/acs.chemmater.6b03244 ↗
29. 10.1021/jacs.8b0855010.1021/jacs.8b08550 ↗
30. 10.1021/acs.organomet.9b0033110.1021/acs.organomet.9b00331 ↗
31. 10.1039/C7FD00055C10.1039/C7FD00055C ↗
32. 10.1021/ja405082810.1021/ja4050828 ↗
33. Zamora-Moreno J. · 2018 · 70110.1016/B978-0-12-812931-9.00032-3 ↗
34. Zamora-Moreno J. · 2018 · 29
35. 10.1002/ejic.20190010710.1002/ejic.201900107 ↗
36. 10.1038/nprot.2016.00110.1038/nprot.2016.001 ↗
37. 10.1021/om100818y10.1021/om100818y ↗
38. 10.1021/ja075725i10.1021/ja075725i ↗
39. 10.1021/om020317310.1021/om0203173 ↗
40. 10.1021/acs.orglett.6b0240610.1021/acs.orglett.6b02406 ↗
41. 10.1039/C8OB02298D10.1039/C8OB02298D ↗
42. 10.1021/om010093910.1021/om0100939 ↗
43. 10.1021/om000948210.1021/om0009482 ↗
44. 10.1021/om010463t10.1021/om010463t ↗
45. 10.1021/om960231810.1021/om9602318 ↗
46. 10.1021/ja102479h10.1021/ja102479h ↗
47. 10.1021/cg301691d10.1021/cg301691d ↗
48. 10.1039/C7DT03670A10.1039/C7DT03670A ↗
49. 10.1021/jacs.5b1268810.1021/jacs.5b12688 ↗
50. 10.1039/C8CE00455B10.1039/C8CE00455B ↗
51. Considering NU-1000 unit cell as C88H44O32Zr6 from CCDC 1580411.
52. 10.1021/ja011319210.1021/ja0113192 ↗
53. 10.1002/adma.20160692910.1002/adma.201606929 ↗
54. 10.1038/s41467-019-09157-210.1038/s41467-019-09157-2 ↗
55. 10.1021/acs.organomet.9b0073510.1021/acs.organomet.9b00735 ↗
56. 10.1039/C9TA02585E10.1039/C9TA02585E ↗
57. 10.1039/D0DT01595D10.1039/D0DT01595D ↗
58. 10.1039/C9TA13524C10.1039/C9TA13524C ↗
59. 10.1038/ncomms1445710.1038/ncomms14457 ↗
60. 10.1021/cm401270b10.1021/cm401270b ↗