Enhanced Catalytic Performance of N-Doped Carbon Sphere-Supported Pd Nanoparticles by Secondary Nitrogen Source Regulation for Formic Acid Dehydrogenation

Min Deng; Anjie Yang; Jun Ma; Chunliang Yang; Tingting Cao; Shuai Yang; Mengqin Yao; Fei Liu; Xiaodan Wang; Jianxin Cao

doi:10.1021/acsami.2c02055

journal article·2022-04-27

Enhanced Catalytic Performance of N-Doped Carbon Sphere-Supported Pd Nanoparticles by Secondary Nitrogen Source Regulation for Formic Acid Dehydrogenation

Min Deng, Anjie Yang, Jun Ma, Chunliang Yang, Tingting Cao, Shuai Yang, Mengqin Yao, Fei Liu, Xiaodan Wang, Jianxin Cao

ACS Applied Materials & Interfaces· Volume 14· Issue 16

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Source abstract

Abstract

The development of catalysts with high selectivity, good catalytic activity, and excellent cycle performance is of significance for the application of formic acid (HCOOH, FA) as a hydrogen support. Herein, Pd is deposited on a series of N-doped carbons, which are prepared by cocarbonization of N-containing zeolite imidazole frameworks (ZIF-8) and other N/C sources (melamine, xylitol, urea, and glucose), for hydrogen generation from FA. The results demonstrate that the introduction of a secondary N/C source further affects the catalytic performance of Pd by adjusting the morphology, specific surface area, N content, and type of carbon. The effects of N atoms and the favorable reaction pathways of FA dehydrogenation were revealed by theoretical calculation. This work will improve the understanding of N doping on the decomposition mechanism of FA and provide a new approach for the rational design of metal-N-C materials.

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials Catalysis & surfaces

OpenAlex topics: Carbon dioxide utilization in catalysis · Metal-Organic Frameworks: Synthesis and Applications · Catalytic Processes in Materials Science

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Guizhou University, Guiyang, Guizhou 550025, China

Guizhou Key Laboratory for Green Chemical and Clean Energy Technology, Guiyang, Guizhou 550025, China

Funding

Natural Science Basic Research Program of Guizhou Province · Innovation Group Project of Education Department in Guizhou Province · One Hundred Person Project of Guizhou Province · Excellent Young Scientific and Technological Talent Program of Guizhou Province · Natural Science Special Foundation of Guizhou University · the cultivation project of Guizhou University · the Ph.D foundation of Guizhou University · Zunyi City Innovative Talent Team Project

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