journal article·2021-09-15

Conjugated Porous Polydiaminophenylsulfone–Triazine Polymer—A High-Performance Anode for Li-Ion Batteries

Quanwei Ma, Jun Zheng, Hongwei Kang, Longhai Zhang, Qianyu Zhang, Hao Li, Rui Wang, Tengfei Zhou, Qi Chen, Axue Liu, Hongbao Li, Chaofeng Zhang

ACS Applied Materials & Interfaces· Volume 13· Issue 36
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Abstract

Organic compounds are promising electrode materials because of their resource sustainability, environmental friendliness, and highly tailorable properties. The porous conjugated polymer shows great potential as an electrode material for its tunable redox nature, conjugated skeleton, and porous structure. Herein, a novel conjugated porous polymer, polydiaminophenylsulfone-triazine, was synthesized by a simple nucleophilic substitution reaction. The conjugated structure and triazine ring can improve the conductivity, charge-transfer efficiency, and physicochemical stability. Also, the porous polymeric framework shows a large specific surface area and high porosity, providing a large contact area with electrolytes and reducing diffusion distance. The polymer demonstrates highly stable cycling performance and good rate capability as an anode for lithium-ion batteries, suggesting a promising strategy to design a competitive electrode material.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Covalent Organic Framework Applications · Advancements in Battery Materials · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Material, Leibniz Research Center of Materials Science, Anhui University, Hefei 230039, China

School of Chemistry and Materials Engineering, Fuyang Normal University, Fuyang 236037, China

Information Materials and Intelligent Sensing Laboratory of Anhui Province, Anhui University, Hefei 230601, China

School of Materials Science and Engineering, Dongguan University of Technology, Dongguan 523808, China

Funding

Fuyang Normal University · National Natural Science Foundation of China · Anhui Province Key Laboratory of Environment-Friendly Polymer Materials · Anhui Province

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