Gradient Hierarchical Hollow Heterostructures of Ti₃C₂T_x@rGO@MoS₂ for Efficient Microwave Absorption

Heterostructure engineering has emerged as a promising approach for creating high-performance microwave absorption materials in various applications such as advanced communications, portable devices, and military fields. However, achieving strong electromagnetic wave attenuation, good impedance matching, and low density in a single heterostructure remains a significant challenge. Herein, a unique structural design strategy that employs a hollow structure coupled with gradient hierarchical heterostructures to achieve high-performance microwave absorption is proposed. MoS 2 nanosheets are uniformly grown onto the double-layered Ti 3 C 2 T x MXene@rGO hollow microspheres through self-assembly and sacrificial template techniques. Notably, the gradient hierarchical heterostructures, comprising a MoS 2 impedance matching layer, a reduced graphene oxide (rGO) lossy layer, and a Ti 3 C 2 T x MXene reflective layer, have demonstrated significant improvements in impedance matching and attenuation capabilities. Additionally, the incorporation of a hollow structure can further improve microwave absorption while reducing the overall composite density. The distinctive gradient hollow heterostructures enable Ti 3 C 2 T x @rGO@MoS 2 hollow microspheres with exceptional microwave absorption properties. The reflection loss value reaches as strong as −54.2 dB at a thin thickness of 1.8 mm, and the effective absorption bandwidth covers the whole Ku-band, up to 6.04 GHz. This work provides an exquisite perspective on heterostructure engineering design for developing next-generation microwave absorbers.