Adsorptive Separation of CO2 by a Hydrophobic Carborane-Based Metal–Organic Framework under Humid Conditions
Source abstract
Abstract
High Resolution Image Download MS PowerPoint Slide We report that the carborane-based metal–organic framework (MOF) m CB-MOF-1 can achieve high adsorptive selectivity for CO 2:N 2 mixtures. This hydrophobic MOF presenting open metal sites shows high CO 2 adsorption capacity and remarkable selectivity values that are maintained even under extremely humid conditions. The comparison of m CB-MOF-1' with MOF-74(Ni) demonstrates the superior performance of the former under challenging moisture operation conditions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Membrane Separation and Gas Transport
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus UAB, 08193Bellaterra, Spain
Instituto de Ciencia Molecular (ICMol), Universidad de Valencia, c/Catedrático José Beltrán, 2, 46980Paterna, Spain
Funding
Generalitat Valenciana · Ministerio de Ciencia e Innovaci?n · Ministerio de Econom?a y Competitividad · Generalitat de Catalunya · China Scholarship Council · H2020 European Research Council
References (64)
Show source-provided references
1. 10.1016/S1001-0742(08)60002-910.1016/S1001-0742(08)60002-9 ↗
2. IEA · 2021
3. 10.1016/S0196-8904(03)00040-210.1016/S0196-8904(03)00040-2 ↗
4. 10.1016/j.fuproc.2005.01.01510.1016/j.fuproc.2005.01.015 ↗
5. 10.1252/jcej.36.36110.1252/jcej.36.361 ↗
6. 10.1021/ef020058u10.1021/ef020058u ↗
7. 10.1016/j.seppur.2017.10.02410.1016/j.seppur.2017.10.024 ↗
8. 10.1016/j.memsci.2016.08.06010.1016/j.memsci.2016.08.060 ↗
9. 10.1016/j.ces.2017.01.07110.1016/j.ces.2017.01.071 ↗
10. 10.1002/adsu.20170009210.1002/adsu.201700092 ↗
11. 10.1016/j.egypro.2017.03.136310.1016/j.egypro.2017.03.1363 ↗
12. 10.1021/ef030003810.1021/ef0300038 ↗
13. 10.1016/j.ces.2009.03.01710.1016/j.ces.2009.03.017 ↗
14. 10.1021/je020161d10.1021/je020161d ↗
15. 10.1038/nature1189310.1038/nature11893 ↗
16. 10.1021/acsami.7b1862010.1021/acsami.7b18620 ↗
17. 10.1021/acs.iecr.7b0371210.1021/acs.iecr.7b03712 ↗
18. 10.1039/C6TA04927C10.1039/C6TA04927C ↗
19. 10.1021/la200547k10.1021/la200547k ↗
20. 10.1039/C7DT01845B10.1039/C7DT01845B ↗
21. 10.1039/C7DT01845B10.1039/C7DT01845B ↗
22. 10.1021/acs.langmuir.5b0083310.1021/acs.langmuir.5b00833 ↗
23. 10.1002/anie.20160393410.1002/anie.201603934 ↗
24. 10.1021/jacs.6b0534510.1021/jacs.6b05345 ↗
25. 10.1038/ncomms522810.1038/ncomms5228 ↗
26. 10.1021/jacs.9b1287910.1021/jacs.9b12879 ↗
27. 10.1039/C5TA05997F10.1039/C5TA05997F ↗
28. 10.1021/acs.iecr.5b0351710.1021/acs.iecr.5b03517 ↗
29. 10.1039/C3CC41564C10.1039/C3CC41564C ↗
30. 10.1002/anie.20130348410.1002/anie.201303484 ↗
31. 10.1021/ja100900c10.1021/ja100900c ↗
32. 10.1021/cr200038x10.1021/cr200038x ↗
33. 10.1039/c5dt00231a10.1039/c5dt00231a ↗
34. Teixidor, F.; Viñas, C. In Science of Synthesis, D E, K.; D S, M., Eds. Thieme: Stuttgart, 2005; Vol. 6, pp 1275–1325.
35. 10.1002/anie.20140735910.1002/anie.201407359 ↗
36. 10.1021/jacs.0c0222810.1021/jacs.0c02228 ↗
37. 10.1038/s41467-022-31267-710.1038/s41467-022-31267-7 ↗
38. 10.1021/ja076167a10.1021/ja076167a ↗
39. 10.1039/b805785k10.1039/b805785k ↗
40. 10.1002/smll.20090008510.1002/smll.200900085 ↗
41. 10.1016/j.ica.2010.08.00710.1016/j.ica.2010.08.007 ↗
42. 10.1039/B927499E10.1039/B927499E ↗
43. 10.1021/cm402094210.1021/cm4020942 ↗
44. 10.1351/PAC-CON-13-01-1310.1351/PAC-CON-13-01-13 ↗
45. 10.1039/C4CC09212K10.1039/C4CC09212K ↗
46. Para-Carborane Is about Five Times More Expensive than Ortho- and Meta-Carborane; Source Katchem Ltd. 2022.
47. 10.1002/anie.20160929510.1002/anie.201609295 ↗
48. 10.1039/D1TC01395E10.1039/D1TC01395E ↗
49. 10.1021/acs.cgd.6b0168210.1021/acs.cgd.6b01682 ↗
50. 10.1002/adma.20180072610.1002/adma.201800726 ↗
51. 10.3390/molecules2417320410.3390/molecules24173204 ↗
52. 10.1021/jacs.0c0100810.1021/jacs.0c01008 ↗
53. 10.1039/D0CC07393H10.1039/D0CC07393H ↗
54. 10.1039/D1DT04065K10.1039/D1DT04065K ↗
55. 10.1021/acs.chemmater.2c0032310.1021/acs.chemmater.2c00323 ↗
56. 10.1002/anie.20046071210.1002/anie.200460712 ↗
57. 10.1021/ic200381f10.1021/ic200381f ↗
58. 10.1021/la401283910.1021/la4012839 ↗
59. 10.1039/C1EE01720A10.1039/C1EE01720A ↗
60. 10.3389/fchem.2022.93970110.3389/fchem.2022.939701 ↗
61. 10.1021/acsomega.0c0118910.1021/acsomega.0c01189 ↗
62. 10.1021/la201774x10.1021/la201774x ↗
63. 10.1016/j.micromeso.2009.11.02610.1016/j.micromeso.2009.11.026 ↗
64. 10.1021/acs.jpclett.2c0069310.1021/acs.jpclett.2c00693 ↗