Pt(II)-Decorated Covalent Organic Framework for Photocatalytic Difluoroalkylation and Oxidative Cyclization Reactions
Source abstract
Abstract
A new covalent organic framework (COF) based on imine bonds was assembled from 2-(4-formylphenyl)-5-formylpyridine and 1,3,6,8-tetrakis(4-aminophenyl)pyrene, which showed an interesting dual-pore structure with high crystallinity. Postmetallation of the COF with Pt occurred selectively at the N donor (imine and pyridyl) in the larger pores. The metallated COF served as an excellent recyclable heterogeneous photocatalyst for decarboxylative difluoroalkylation and oxidative cyclization reactions.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, Arkansas 72701, United States
Department of Chemical and Biological Engineering, The University of Sheffield, Sheffield S1 3JD, U.K.
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Zanjan 45137-66731, Iran
DICATECh, Politecnico di Bari, Bari I-70125, Italy
Institute for Nano Science and Engineering, University of Arkansas, Fayetteville, Arkansas 72701, United States
Department of Chemistry and Physics, Florida Gulf Coast University, Fort Myers, Florida 33965, United States
Department of Chemistry, University of Isfahan, Isfahan 81746-73441, Iran
Funding
University of Arkansas · Lembaga Pengelola Dana Pendidikan · National Institute of General Medical Sciences
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