journal article·2023-02-08

Anticorrosion Coating with Heterogeneous Assembly of Nanofillers Modulated by a Magnetic Field

Lu Pengpeng, Fu Xue, Li Xin, Xu Li, Yong Fan, Jie Zhao, Limei Tian, Jiyu Sun, Luquan Ren

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Abstract

An anticorrosive coating with randomly distributed passive barriers and regionally enriched active corrosion inhibitors is developed by integrating mica nanosheets (MNSs) and magnetic-responsive core–shell mesoporous nanoparticles with 2-mercaptobenzothiazole (Fe 3 O 4 @mSiO 2 /MBT) under magnetic field incubation. The bottom enriched Fe 3 O 4 @mSiO 2 /MBT rapidly releases the MBT to form a passivation layer on corrosion sites, enhancing the corrosion inhibition efficiency by 30.36% compared with the control (NP 0.7 EP-R). The impedance modulus | Z | 0.01 Hz of the sample (NP 0.7 /MNS 0.5 /EP) increases by five orders of magnitude compared with that of its control (NP 0.7 /MNS 0 EP) after 30 days of corrosion immersion. NP 0.7 /MNS 0.5 /EP exhibited the lowest corrosion rate (3.984 × 10 –5 mm/year) as compared to the other samples. Notably, the coating in a fractured state still maintains superior corrosion inhibition even after 40 day salt spray testing. The differentiated distribution of nanofillers was well confirmed by optical microscopy and SEM-EDS, and the synergistic effect of the active/passive integrated anticorrosive coating with merits of both comprehensive protection and fast responsiveness was systematically explored.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Material Properties and Applications · Advanced Theoretical and Applied Studies in Material Sciences and Geometry · Surface Treatment and Coatings

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Bionic Engineering, Ministry of Education, Jilin University, Changchun130022, China

College of Chemistry, Jilin University, Changchun130012, China

Funding

Natural Science Foundation of Guangxi Province · People's Government of Jilin Province · Jilin University · Ministry of Industry and Information Technology of the People's Republic of China · Education Department of Jilin Province

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