Asymmetric Sodiophilic Host Based on a Ag-Modified Carbon Fiber Framework for Dendrite-Free Sodium Metal Anodes

Sodium (Na) metal is considered a promising anode material for high-energy Na batteries due to its high theoretical capacity and abundant resources. However, uncontrollable dendrite growth during the repeated Na plating/stripping process leads to the issues of low Coulombic efficiency and short circuits, impeding the practical applications of Na metal anodes. Herein, we propose a silver-modified carbon nanofiber (CNF@Ag) host with asymmetric sodiophilic features to effectively improve the deposition behavior of Na metal. Both density functional theory (DFT) calculations and experiment results demonstrate that Na metal can preferentially nucleate on the sodiophilic surface with Ag nanoparticles and uniformly deposit on the whole CNF@Ag host with a "bottom-up growth" mode, thus preventing unsafe dendrite growth at the anode/separator interface. The optimized CNF@Ag framework exhibits an excellent average Coulombic efficiency of 99.9% for 500 cycles during Na plating/stripping at 1 mA cm^-2 for 1 mAh cm^-2. Moreover, the CNF@Ag-Na symmetric cell displays stable cycling for 500 h with a low voltage hysteresis at 2 mA cm^-2. The CNF@Ag-Na//Na₃V₂(PO₄)₃ full cell also presents a high reversible specific capacity of 102.7 mAh g^-1 for over 200 cycles at 1 C. Therefore, asymmetric sodiophilic engineering presents a facile and efficient approach for developing high-performance Na batteries with high safety and stable cycling performance.