journal article·2018-03-21

Highly Ordered Hierarchical Pt and PtNi Nanowire Arrays for Enhanced Electrocatalytic Activity toward Methanol Oxidation

Changzheng Wang, Yang Zhang, Yajun Zhang, Ping Xu, Cuimin Feng, Tao Chen, Tao Guo, Fengnan Yang, Qiang Wang, Jingxiao Wang, Mengtong Shi, Louzhen Fan, Shaowei Chen

ACS Applied Materials & Interfaces· Volume 10· Issue 11
Publisher page

Abstract

Highly ordered hierarchical Pt and PtNi nanowire arrays were prepared using CdS hierarchical nanowire arrays (HNWAs) as sacrificial templates and demonstrated high electrochemical active surface areas. For the resulting Pt HNWAs sample, the peak current for methanol oxidation at +0.74 V was almost 1 order of magnitude higher than that of Pt solid nanowire arrays prepared in a similar manner but without the use of CdS template, and the addition of a Ni cocatalyst effectively enhanced the tolerance against CO poisoning. The results demonstrated that highly ordered Pt and PtNi HNWAs may be exploited as promising anode catalysts in the application of direct methanol fuel cells.
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Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Advanced battery technologies research · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory of Urban Stormwater System and Water Environment, Ministry of Education, Beijing University of Civil Engineering and Architecture, Beijing 100044, China

Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences, Beijing 100083, China

Laboratory for Micro-sized Functional Materials, College of Elementary Education, Capital Normal University, Beijing 100048, China

Department of Chemistry, Beijing Normal University, Beijing 100875, China

Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, United States

Funding

National Natural Science Foundation of China

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