journal article·2023-05-17

Application of Silver-Loaded Halloysite Nanotubes in Flame Retardant and Smoke-Suppressive Coating for Polyester-Cotton Fabric

Liangyuan Qi, Wei Cai, Weijie Zhang, Bangyu Wang, Wensheng Li, Xiaohui Jin, Liang Chen, Bin Yu, Yuan Hu, Weiyi Xing

ACS Applied Materials & Interfaces· Volume 15· Issue 19
Publisher page

Abstract

Despite the wide applications in clothing, furniture, and transportation, the well-known "scaffolding effect" in polyester-cotton fabric has caused significant fire hazards compared to sole polyester or cotton fabrics. Therefore, it is of practical significance to endow polyester-cotton fabric with excellent fire safety. In this work, an organic-inorganic composite coating comprising nitrogen-phosphorus-silicon-containing flame retardant and silver nanoparticle-loaded halloysite nanotubes (Ag@HNTs) was designed and prepared to improve the fire safety of polyester-cotton fabrics. Microscale combustion colorimeter results indicated that the peak heat release rate of the modified polyester-cotton fabric with such a composite coating was reduced by 47%. Meanwhile, it could self-extinguish in 9 s after being ignited, and the limiting oxygen index was up to 25%, indicating excellent fire safety. In addition, the total smoke release of the coated polyester-cotton fabric was reduced by 21%, illustrating that the coating of Ag@HNTs could eliminate the smoke generated. The treated fabric also exhibited superior water resistance. Flame retardant mechanisms were well investigated using thermogravimetric analysis-infrared spectrometry analysis and chemiluminescence by studying the gaseous degradation products and hydroxyl radical in the gas phase. This work provides an effective approach to fabricating high-performance flame retardant and smoke-suppressive coatings for textiles.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Clay minerals and soil interactions · Iron oxide chemistry and applications · Layered Double Hydroxides Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Fire Science, University of Science and Technology of China, Hefei, Anhui 230026, China

Funding

University of Science and Technology of China · Youth Innovation Promotion Association of the Chinese Academy of Sciences · Ministry of Education of the People's Republic of China · National Natural Science Foundation of China

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