journal article·2017-04-26

Ultramicroporous Carbon through an Activation-Free Approach for Li–S and Na–S Batteries in Carbonate-Based Electrolyte

Lei Hu, Yue Lu, Tianwen Zhang, Tao Huang, Yongchun Zhu, Yitai Qian

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Abstract

We report an activation-free approach for fabricating ultramicroporous carbon as an accommodation of sulfur molecules for Li–S and Na–S batteries applications in carbonate-based electrolyte. Because of the high specific surface area of 967 m 2 g –1, as well as 51.8% of the pore volume is contributed by ultramicropore with pore size less than 0.7 nm, sulfur cathode exhibits superior electrochemical behavior in carbonate-based electrolyte with a capacity of 507.9 mA h g –1 after 500 cycles at 2 C in Li–S batteries and 392 mA h g –1 after 200 cycles at 1 C in Na–S batteries, respectively.
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Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Supercapacitor Materials and Fabrication

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Affiliations

School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, P. R. China

Funding

Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · The Fundamental Research Funds for the Central Universities · Anhui Provincial Natural Science Foundation

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