Highly Efficient SO₂ Sensing by Light-Assisted Ag/PANI/SnO₂ at Room Temperature and the Sensing Mechanism

Sulfur dioxide (SO₂) is one of the most hazardous and common environmental pollutants. However, the development of room-temperature SO₂ sensors is seriously lagging behind that of other toxic gas sensors due to their poor recovery properties. In this study, a light-assisted SO₂ gas sensor based on polyaniline (PANI) and Ag nanoparticle-comodified tin dioxide nanostructures (Ag/PANI/SnO₂) was developed and exhibited remarkable SO₂ sensitivity and excellent recovery properties. The response of the Ag/PANI/SnO₂ sensor (20.1) to 50 ppm SO₂ under 365 nm ultraviolet (UV) light illumination at 20 °C was almost 10 times higher than that of the pure SnO₂ sensor. Significantly, the UV-assisted Ag/PANI/SnO₂ sensor had a rapid response time (110 s) and recovery time (100 s) to 50 ppm SO₂, but in the absence of light, the sensors exhibited poor recovery performance or were even severely and irreversibly deactivated by SO₂. The UV-assisted Ag/PANI/SnO₂ sensor also exhibited excellent selectivity, superior reproducibility, and satisfactory long-term stability at room temperature. The increased charge carrier density, improved charge-transfer capability, and the higher active surface of the Ag/PANI/SnO₂ sensor were revealed by electrochemical measurements and endowed with high SO₂ sensitivity. Moreover, the light-induced formation of hot electrons in a high-energy state in Ag/PANI/SnO₂ significantly facilitated the recovery of SO₂ by the gas sensor.