journal article·2017-09-06

Combustion-Assisted Photonic Annealing of Printable Graphene Inks via Exothermic Binders

Ethan B. Secor, Theodore Z. Gao, Manuel H. Dos Santos, Shay G. Wallace, Karl W. Putz, Mark C. Hersam

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Abstract

High-throughput and low-temperature processing of high-performance nanomaterial inks is an important technical challenge for large-area, flexible printed electronics. In this report, we demonstrate nitrocellulose as an exothermic binder for photonic annealing of conductive graphene inks, leveraging the rapid decomposition kinetics and built-in energy of nitrocellulose to enable versatile process integration. This strategy results in superlative electrical properties that are comparable to extended thermal annealing at 350 °C, using a pulsed light process that is compatible with thermally sensitive substrates. The resulting porous microstructure and broad liquid-phase patterning compatibility are exploited for printed graphene microsupercapacitors on paper-based substrates.
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Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Supercapacitor Materials and Fabrication · Graphene research and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Materials Science and Engineering and ⊥Department of Chemistry, Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208, United States

Funding

Air Force Research Laboratory · U.S. Department of Defense · Northwestern University

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