Fast Photoinduced Large Deformation of Colloidal Spheres from a Novel 4-arm Azobenzene Compound
Source abstract
Abstract
A novel 4-arm shaped amphiphilic azobenzene compound was synthesized. The tetraphenylethylene (TPE) core precursor was prepared and further modified by azo coupling reaction at the four peripheral groups. Colloidal spheres could be directly prepared by self-assembly of the prepared amphiphilic azobenzene compound in selective solvents (THF/H2O), which were characterized by using transmission electron microscopy. The colloid diameters could be controlled by adjusting the initial compound concentration and water-adding rate in the preparation processes. By irradiation with visible linearly polarized LED light (450 nm), fast photoinduced deformation of the colloidal spheres along the polarization direction was observed. A very large deformation degree (l/d > 4) could be easily obtained.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Liquid Crystal Research Advancements · Photochromic and Fluorescence Chemistry · Photonic Crystals and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Chemical Engineering, Key Laboratory of Advanced Materials (MOE), Tsinghua University, Beijing 100084, People’s Republic of China
Funding
National Natural Science Foundation of China
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