Evaluation of an Ionic Porous Organic Polymer for Water Remediation
Source abstract
Abstract
The targeted synthesis of a novel ionic porous organic polymer (iPOP) was reported. The compound (denoted as QUST-iPOP-1) was built up through a quaternization reaction of tris(4-imidazolylphenyl)amine and cyanuric chloride, and then benzyl bromide was added to complete the quaternization of the total imidazolyl units. It featured a special exchangeable Cl–/Br–-rich structure with high permanent porosity and wide pore size distribution, enabling it to rapidly and effectively remove environmentally toxic oxo-anions including Cr2O72–, MnO4–, and ReO4– and anionic organic dyes with different sizes including methyl blue, Congo red, and methyl orange from water. Notably, QUST-iPOP-1 showed ultra-high capacity values for radioactive TcO4– surrogate anions (MnO4– and ReO4–), Cr2O72–, methyl blue, and Congo red, and these were comparable to some reported compounds of exhaustive research. Furthermore, the relative removal rate was high even when other concurrent anions existed.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications · Luminescence and Fluorescent Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Eco-chemical Engineering, Key Laboratory of Optic-electric Sensing and Analytical Chemistry of Life Science, Taishan Scholar Advantage and Characteristic Discipline Team of Eco Chemical Process and Technology, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China
Jiangsu Key Laboratory of Materials and Technology for Energy Conversion, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China
Shandong Engineering Research Center for Marine Environment Corrosion and Safety Protection, College of Environment and Safety Engineering, Qingdao University of Science and Technology, Qingdao 266042, P. R. China
Funding
Shandong Province · National Natural Science Foundation of China · Natural Science Foundation of Shandong Province
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