journal article·2019-06-26

Self-Template Synthesis of Nanoporous VO2-Based Films: Localized Surface Plasmon Resonance and Enhanced Optical Performance for Solar Glazing Application

Shiwei Long, Xun Cao, Rong Huang, Fang Xu, Ning Li, Aibin Huang, Guangyao Sun, Shanhu Bao, Hongjie Luo, Ping Jin

ACS Applied Materials & Interfaces· Volume 11· Issue 25
Publisher page

Abstract

Poly(tetrafluoroethylene) (Teflon) has been selected as the self-template structural material in the preparation of VO2 films using a reactive magnetron sputtering method and post-annealing process. VO2 films with spontaneous random nanoporous structures growing on quartz glasses have been deliberately established via bottom-up processing through this novel and facile approach. The nanoporous VO2 films exhibit an excellent optical performance based on the localized surface plasmon resonance, with ultrahigh luminous transmittance (Tlum-L) up to 78.0% and the promoted solar modulation ability (ΔTsol) of 14.1%. Meanwhile, the ingenious microstructure of the film provides an antireflection function from multiple perspectives on visible light and indicates the potential of the windshield on vehicles for smart solar modulation. The nanoporous films expand the practical application of thermochromic VO2 to a fire-new field, breaking the optical performance envelope of the single-layer dense VO2 film away, and offering a universal method to prepare homogeneous nanoporous structures for thin films.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Transition Metal Oxide Nanomaterials · TiO2 Photocatalysis and Solar Cells · Pigment Synthesis and Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

University of Chinese Academy of Sciences, Beijing 100049, China

Key Laboratory of Polar Materials and Devices, Ministry of Education, East China Normal University, Shanghai 200241, China

Department of Materials Science and Engineering, College of Science, China University of Petroleum Beijing, No. 18 Fuxue Road, Beijing 102249, China

School of Materials Science and Engineering, Shanghai University, Shangda Road 99, Baoshan, Shanghai 200444, China

Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology, Nagoya 463-8560, Japan

Funding

Youth Innovation Promotion Association of the Chinese Academy of Sciences · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · State Key Laboratory of High Performance Ceramics and Superfine Microstructures · Anhui Province

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