journal article·2016-12-21

A Safe High-Performance All-Solid-State Lithium–Vanadium Battery with a Freestanding V2O5 Nanowire Composite Paper Cathode

Yue Zhang, Jingyuan Lai, Yudong Gong, Yongming Hu, Jin Liu, Chunwen Sun, Zhong Lin Wang

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Abstract

The electronic conductivity and structural stability are still challenges for vanadium pentoxide (V 2 O 5 ) as cathode materials in batteries. Here, we report a V 2 O 5 nanowire–reduced graphene oxide (rGO) composite paper for direct use as a cathode without any additives for high-temperature and high-safety solid polymer electrolyte [PEO-MIL-53(Al)-LiTFSI] lithium–vanadium batteries. The batteries can show a fast and stable lithium-ion-storage performance in a wide voltage window of 1.0–4.0 V versus Li + /Li at 80 °C, in which with an average capacity of 329.2 mAh g –1 at 17 mA g –1 and a stable cycling performance over 40 cycles are achieved. The excellent electrochemical performance is mainly ascribed to integration of the electronic conductivity of rGO and interconnected networks of the V 2 O 5 nanowires and solid electrolyte. This is a promising lithium battery for flexible and highly safe energy-storage devices.
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Research context

OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing Institute of Nanoenergy and Nanosystems, Chinese Academy of Sciences; National Center for Nanoscience and Technology (NCNST), Beijing 100083, China

Hubei Collaborative Innovation Centre for Advanced Organic Chemical Materials, State Key Lab of Ferro & Piezoelectric Materials and Devices of Hubei Province Faculty, Faculty of Physics and Electronic Science, Hubei University, Wuhan 430062, China

School of Metallurgy and Environment, Central South University, Changsha 410083, China

School of Material Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0245, United States

Funding

Central South University · Ministry of Science and Technology of the People's Republic of China · National Natural Science Foundation of China · Chinese Academy of Engineering · Thousands Talents Program for Pioneer Researcher and His Innovation Team

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