DataVXACS Applied Materials & InterfacesPaper
journal article·2019-03-06

Enhancing Energetic Performance of Multinuclear Ag(I)-Cluster MOF-Based High-Energy-Density Materials by Thermal Dehydration

Xiaohui Ma, Chao Cai, Wujuan Sun, Weiming Song, Yulong Ma, Xiangyu Liu, Gang Xie, Sanping Chen, Shengli Gao

ACS Applied Materials & Interfaces· Volume 11· Issue 9
Publisher page
Source abstract

Abstract

It is an enormous challenge to construct high-energy-density materials meeting simultaneously requirements of high energy and excellent stability. In this work, the reaction of a Ag(I) ion with a nitrogen-rich ligand, 1H-tetrazole-5-acetic acid (H2tza), leads to a novel Ag7-cluster metal–organic framework, [Ag7(tza)3(Htza)2(H2tza)(H2O)] (1), with remarkable high-energy content, stability, and insensitivity. Dramatically, the heating-dehydrated process of 1 produces a new stable energetic material, [Ag7(tza)3(Htza)2(H2tza)] (1a), which features superior energy and undiminished safety performance compared to those of 1.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Energetic Materials and Combustion · Boron and Carbon Nanomaterials Research · Thermal and Kinetic Analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of High-efficiency Coal Utilization and Green Chemical Engineering, College of Chemistry and Chemical Engineering, Ningxia University,Yinchuan 750021, China

College of Chemistry & Chemical Engineering, Xi’an ShiYou University, Xi’an 710065, China

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China

Funding

National Natural Science Foundation of China · Ningxia Province · Graduate Innovative Experiment

References (27)

Show source-provided references
1. 10.1002/anie.201606894;10.1002/anie.201606894; ↗
2. 10.1002/anie.20150674410.1002/anie.201506744 ↗
3. 10.1021/jacs.5b0071410.1021/jacs.5b00714 ↗
4. 10.1002/anie.20150745610.1002/anie.201507456 ↗
5. 10.1002/asia.20130124210.1002/asia.201301242 ↗
6. 10.1002/anie.20160637810.1002/anie.201606378 ↗
7. 10.1021/ja106892a10.1021/ja106892a ↗
8. 10.1021/jacs.6b0381910.1021/jacs.6b03819 ↗
9. 10.1016/j.ccr.2015.08.00610.1016/j.ccr.2015.08.006 ↗
10. 10.1039/C7CC00545H10.1039/C7CC00545H ↗
11. 10.1016/j.matlet.2018.12.02810.1016/j.matlet.2018.12.028 ↗
12. 10.1039/C4GC02184C10.1039/C4GC02184C ↗
13. 10.1021/acs.inorgchem.8b0260210.1021/acs.inorgchem.8b02602 ↗
14. 10.1002/1521-3757(20000616)112:12<2161::AID-ANGE2161>3.0.CO;2-610.1002/1521-3757(20000616)112:12<2161::AID-ANGE2161>3.0.CO;2-6 ↗
15. 10.1002/ange.20150920910.1002/ange.201509209 ↗
16. 10.1016/j.ccr.2007.07.01810.1016/j.ccr.2007.07.018 ↗
17. 10.1039/C4CE01388C10.1039/C4CE01388C ↗
18. 10.1021/ic034758610.1021/ic0347586 ↗
19. 10.1021/ja054913a10.1021/ja054913a ↗
20. 10.1021/ic700415w10.1021/ic700415w ↗
21. 10.1021/ja201345510.1021/ja2013455 ↗
22. 10.1021/jp502857d10.1021/jp502857d ↗
23. 10.1063/1.166790810.1063/1.1667908 ↗
24. Köhler J. · 199810.1002/9783527625826 ↗
25. 10.1021/ja209640k10.1021/ja209640k ↗
26. 10.1039/C7CC03869K10.1039/C7CC03869K ↗
27. 10.1002/anie.20130711810.1002/anie.201307118 ↗