Two Novel Polyoxometalate-Encapsulated Metal–Organic Nanotube Frameworks as Stable and Highly Efficient Electrocatalysts for Hydrogen Evolution Reaction
Source abstract
Abstract
Two novel polyoxometalate (POM)-encapsulated metal–organic nanotube (MONT) framework crystalline materials with unprecedented copper-mixed ligands, HUST-200 and HUST-201, have been successfully synthesized by an effective synthesis strategy. The encapsulation not only provides a shield to increase the chemical stability, but also does not affect its catalytic activity, and, therefore, the crystalline materials are very active for HER (H+ can diffuse easily through the pores of the MONTs). Remarkably, HUST-200 displays a low overpotential of 131 mV (catalytic current density is equal to 10 mA·cm–2). This work thus offers a new way for devising HER electrocatalysts with low cost using POM-encapsulated MONT frameworks.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Electrocatalysts for Energy Conversion · Polyoxometalates: Synthesis and Applications · Metal-Organic Frameworks: Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
School of Materials Science and Engineering, College of Chemical and Environmental Engineering, Harbin University of Science and Technology (HUST), No. 4, Linyuan Road, Harbin 150040, China
College of Materials Science and Engineering, Heilongjiang Provincial Key Laboratory of Polymeric Composite Materials, Qiqihar University, No. 42, Wenhua Street, Qiqihar 161006, China
Instituto de Ciencia Molecular, Departamento de Química Inorgánica, Universidad de Valencia, C/Catedrático José Beltrán, 2, 46980 Paterna, Spain
Funding
Generalitat Valenciana · Ministerio de Econom?a y Competitividad · Natural Science Foundation of Heilongjiang Province · National Natural Science Foundation of China
References (66)
Show source-provided references
1. 10.1038/3510459910.1038/35104599 ↗
2. 10.1126/science.110319710.1126/science.1103197 ↗
3. 10.1039/b820837a10.1039/b820837a ↗
4. 10.1021/cr100232610.1021/cr1002326 ↗
5. 10.1126/science.aad499810.1126/science.aad4998 ↗
6. 10.1021/acsami.8b0154110.1021/acsami.8b01541 ↗
7. 10.1002/adma.20160227010.1002/adma.201602270 ↗
8. 10.1016/j.carbon.2018.06.05810.1016/j.carbon.2018.06.058 ↗
9. 10.1002/anie.20150141910.1002/anie.201501419 ↗
10. 10.1002/anie.20170723810.1002/anie.201707238 ↗
11. 10.1021/jacs.5b0268810.1021/jacs.5b02688 ↗
12. 10.1002/anie.20150569110.1002/anie.201505691 ↗
13. 10.1021/acsami.7b0910810.1021/acsami.7b09108 ↗
14. 10.1021/acssuschemeng.8b0157510.1021/acssuschemeng.8b01575 ↗
15. 10.1021/acsami.6b1324410.1021/acsami.6b13244 ↗
16. 10.1039/c7cc09223g10.1039/c7cc09223g ↗
17. 10.1038/378703a010.1038/378703a0 ↗
18. 10.1126/science.111627510.1126/science.1116275 ↗
19. 10.1021/cr300014x10.1021/cr300014x ↗
20. 10.1002/adma.20160544610.1002/adma.201605446 ↗
21. 10.1002/adma.20160613410.1002/adma.201606134 ↗
22. 10.1039/c6cs00724d10.1039/c6cs00724d ↗
23. 10.1021/am404256410.1021/am4042564 ↗
24. 10.1021/acs.cgd.8b0076610.1021/acs.cgd.8b00766 ↗
25. 10.1039/c1jm11153a10.1039/c1jm11153a ↗
26. 10.1039/c2cc31527k10.1039/c2cc31527k ↗
27. 10.1021/ja309158a10.1021/ja309158a ↗
28. 10.1002/chem.20130478410.1002/chem.201304784 ↗
29. 10.1021/ja805920t10.1021/ja805920t ↗
30. 10.1038/354056a010.1038/354056a0 ↗
31. 10.1002/adfm.20130051010.1002/adfm.201300510 ↗
32. 10.1021/cg401529u10.1021/cg401529u ↗
33. 10.1039/c3cc46779a10.1039/c3cc46779a ↗
34. 10.1021/ja061716i10.1021/ja061716i ↗
35. 10.1021/ja077163910.1021/ja0771639 ↗
36. 10.1039/c6ta10382k10.1039/c6ta10382k ↗
37. 10.1039/b502666k10.1039/b502666k ↗
38. 10.1038/srep0261610.1038/srep02616 ↗
39. 10.1021/ja211720610.1021/ja2117206 ↗
40. 10.1021/ja00058a02710.1021/ja00058a027 ↗
41. 10.1002/cctc.20170192610.1002/cctc.201701926 ↗
42. 10.1021/cr500390v10.1021/cr500390v ↗
43. 10.1021/cr960403a10.1021/cr960403a ↗
44. 10.1002/adma.20060241010.1002/adma.200602410 ↗
45. 10.1039/b925947c10.1039/b925947c ↗
46. 10.1002/celc.20170121010.1002/celc.201701210 ↗
47. 10.1021/ja201165c10.1021/ja201165c ↗
48. 10.3390/magnetochemistry201000110.3390/magnetochemistry2010001 ↗
49. 10.1021/ja400303f10.1021/ja400303f ↗
50. 10.1021/ja002572p10.1021/ja002572p ↗
51. 10.1107/s010876818500206310.1107/s0108768185002063 ↗
52. 10.1021/ja509960n10.1021/ja509960n ↗
53. 10.1021/jacs.7b0155910.1021/jacs.7b01559 ↗
54. 10.1021/cm702938q10.1021/cm702938q ↗
55. Wang E. B. · 1998
56. 10.1021/cm401400m10.1021/cm401400m ↗
57. 10.1002/anie.20110315510.1002/anie.201103155 ↗
58. 10.1002/chem.20150133710.1002/chem.201501337 ↗
59. 10.1007/430_2017_610.1007/430_2017_6 ↗
60. 10.1038/ncomms141510.1038/ncomms1415 ↗
61. 10.1021/ja201269b10.1021/ja201269b ↗
62. 10.1002/ange.20150752910.1002/ange.201507529 ↗
63. 10.1002/adma.20160583810.1002/adma.201605838 ↗
64. 10.1039/c3cs60468c10.1039/c3cs60468c ↗
65. 10.1007/s12274-016-1281-910.1007/s12274-016-1281-9 ↗
66. 10.1021/ic201571n10.1021/ic201571n ↗