Confining Polyoxometalate Clusters into Porous Aromatic Framework Materials for Catalytic Desulfurization of Dibenzothiophene
Source abstract
Abstract
Removal of notorious sulfur compounds to produce low-sulfur-content (≤10 ppm) diesel is necessary and vital for modern industry and environmental protection. A new type of inorganic–organic hybrid material has been designed and synthesized via confining molybdenum-containing polyoxometalate (POM) clusters within porous aromatic framework-1 (PAF-1) cavities named POM–PAF-1. Deep oxidative desulfurization experiments reveal that POM–PAF-1 possesses excellent reactivity under mild conditions, exemplified by a sulfur removal degree of 98.5% dibenzothiophene within 30 min at 30 °C. The improvement in oxidative desulfurization reactivity from traditional porous POM-based catalysts is owing to uniform POMs and lipophilic and porous PAF-1. The high performance of POM–PAF-1 in terms of excellent reactivity and good stability means it has potential in new heterogeneous catalysis.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Polyoxometalates: Synthesis and Applications · Catalysis and Hydrodesulfurization Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Key Laboratory of Polyoxometalates Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, P. R. China
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China
College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, P. R. China
Funding
State Administration of Foreign Experts Affairs · Ministry of Education of the People's Republic of China · National Natural Science Foundation of China · Jilin Association of Science and Technology · Jilin Scientific and Technological Development Program · State Key Lab Open Projects · Jilin Education Office
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