Block Copolymer Nanoparticles Prepared via Polymerization-Induced Self-Assembly Provide Excellent Boundary Lubrication Performance for Next-Generation Ultralow-Viscosity Automotive Engine Oils

Core cross-linked poly(stearyl methacrylate)-poly(benzyl methacrylate)-poly(ethylene glycol dimethacrylate) [S₃₁-B₂₀₀-E₂₀] triblock copolymer nanoparticles were synthesized directly in an industrial mineral oil via polymerization-induced self-assembly (PISA). Gel permeation chromatography analysis of the S₃₁-B₂₀₀ diblock copolymer precursor chains indicated a well-controlled reversible addition-fragmentation chain transfer dispersion polymerization, while transmission electron microscopy, dynamic light-scattering (DLS), and small-angle X-ray scattering studies indicated the formation of well-defined spheres. Moreover, DLS studies performed in THF, which is a common solvent for the S and B blocks, confirmed successful covalent stabilization because well-defined solvent-swollen spheres were obtained under such conditions. Tribology experiments using a mini-traction machine (MTM) indicated that 0.50% w/w dispersions of S₃₁-B₂₀₀-E₂₀ spheres dramatically reduce the friction coefficient of base oil within the boundary lubrication regime. Given their efficient and straightforward PISA synthesis at high solids, such nanoparticles offer new opportunities for the formulation of next-generation ultralow-viscosity automotive engine oils.