Bioinspired Superhydrophobic/Superhydrophilic Janus Copper Foam for On-Demand Oil/Water Separation

Superwettable Janus membranes with unique interfacial characteristics have versatile applications in oil/water separation, microfluid transportation, and membrane distillation. However, it remains a significant challenge to simply fabricate three-dimensional (3D) metallic foams with Janus superwettability using a facile and environment-friendly method. In this study, a novel method is present to construct a Janus copper foam (CF) by combining superhydrophobicity and superhydrophilicity into CF. Based on gravity, the water in the light oil (LO)/water mixture can be transported from the superhydrophilic (SHL) side to the superhydrophobic (SHB) side, while the heavy oil (HO) in the HO/water/mixture can be transported from the SHB side to the SHL side. Therefore, cylindrical Janus oil/water separation devices with superior separation efficiency and excellent repeatability can achieve on-demand oil/water separation effortlessly. This design and fabrication method offers a novel avenue for the preparation of Janus interface materials for practical applications in liquid transportation, sensor devices, energy materials, and oil spills.