DataVXACS Applied Materials & InterfacesPaper
journal article·2016-09-07

Perylene-Based All-Organic Redox Battery with Excellent Cycling Stability

Adriana Iordache, Virginie Delhorbe, Michel Bardet, Lionel Dubois, Thibaut Gutel, Lionel Picard

ACS Applied Materials & Interfaces· Volume 8· Issue 35
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Source abstract

Abstract

Organic materials derived from biomass can constitute a viable option as replacements for inorganic materials in lithium-ion battery electrodes owing to their low production costs, recyclability, and structural diversity. Among them, conjugated carbonyls have become the most promising type of organic electrode material as they present high theoretical capacity, fast reaction kinetics, and quasi-infinite structural diversity. In this letter, we report a new perylene-based all-organic redox battery comprising two aromatic conjugated carbonyl electrode materials, the prelithiated tetra-lithium perylene-3,4,9,10-tetracarboxylate (PTCLi6) as negative electrode material and the poly(N-n-hexyl-3,4,9,10-perylene tetracarboxylic)imide (PTCI) as positive electrode material. The resulting battery shows promising long-term cycling stability up to 200 cycles. In view of the enhanced cycling performances, the two organic materials studied herein are proposed as suitable candidates for the development of new all-organic lithium-ion batteries.
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Research context

Energy storage

OpenAlex topics: Advanced battery technologies research · Advanced Battery Materials and Technologies · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Université Grenoble Alpes, F-38000 Grenoble, France

Commissariat à l’énergie atomique et aux énergies alternatives - Direction de la recherche technologique - Laboratoire d’innovation pour les technologies des énergies nouvelles et les nanomatériaux - Département de l’électricité de l’hydrogène pour les tranports - Service des composants pour générateurs électrochimiques, 17 Rue des Martyrs, F-38054 Grenoble, France

Commissariat à l’énergie atomique et aux énergies alternatives - Direction de la recherche fondamentale - Institut nanosciences et cryogénie - Modélisation et exploration des matériaux, UMR-E CEA-UJF, 17 Rue des Martyrs, F-38054 Grenoble, France

Commissariat à l’énergie atomique et aux énergies alternatives - Direction de la recherche fondamentale - Institut nanosciences et cryogénie - Systèmes moléculaires et nanomatériaux pour l’énergie et la santé, UMR-E CEA-UJF, 17 Rue des Martyrs, F-38054 Grenoble, France

Funding

Commissariat a l'Energie Atomique et aux Energies Alternatives

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