Fabrication of PVDF/BaTiO₃/CNT Piezoelectric Energy Harvesters with Bionic Balsa Wood Structures through 3D Printing and Supercritical Carbon Dioxide Foaming

Piezoelectric energy harvesters have received widespread attention in recent decades due to their inimitable electrical energy conversion methods. However, traditional polymer/piezoceramic materials and 2D thin-film structures have limited output performance, making them difficult to be efficiently applied in the collection of discrete mechanical energy. Here, new ternary composite powders were successfully developed by the ultrasonic coating method, and array structural devices with the construction of micropores were prepared using selective laser sintering (SLS) and supercritical carbon dioxide foaming (Sc-CO 2 ) technologies. Coating carbon nanotubes improved the polarization efficiency of poly(vinylidene fluoride)/barium titanate (PVDF/BaTiO 3 ) composites, which made it easy to perfectly combine the BaTiO 3 piezoelectric constant and the flexibility of PVDF, promoting d 33 from 0.7 to 2.6 pc/N. In addition, simulations and experiments simultaneously proved that SLS parts with high array densities amplified piezoelectric outputs because of a greater compression deformation in the vertical direction. Meanwhile, under the synergistic effect of SLS and Sc-CO 2, 3D bionic balsa wood structure foams were successfully fabricated, which took advantage of the normal space, expanded the stress–strain effect, and improved the piezoelectric output capability. Excitingly, the prepared foam could directly produce 19.3 V and 415 nA piezoelectric output to charge a 1 μF commercial capacitor to 5.03 V within 180 s, which surpassed most of the PVDF piezoelectric energy harvesters reported thus far. This work has an excellent innovative and practical value in enriching the types of piezoelectric materials for SLS 3D printing and the design of 3D piezoelectric structures.